Functionalized fluorinated arylethers by ring-opening of 1,2,3,4-tetrafluorodibenz[b,f][1,4]oxazepine

被引：4
|
作者：
Doherty, B [1 ]
Nieuwenhuyzen, M [1 ]
Saunders, GC [1 ]
Sloan, MS [1 ]
机构：
[1] Queens Univ Belfast, Sch Chem, Belfast BT9 5AG, Antrim, North Ireland
来源：
JOURNAL OF FLUORINE CHEMISTRY | 2003年 / 119卷 / 01期
关键词：
dibenzoxazepine; arylethers; crystal structure; ring-opening;
D O I：
10.1016/S0022-1139(02)00245-2
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Treatment of 1,2,3,4-tetrafluorodibenz[b,f][1,4]oxazepine with acetyl or benzoyl chloride produces the fluorinated aryl ethers bearing amide and aldehyde functionalities, RCONHC6H4-2-OC6F4CHO-2 (2a R = Ph; 2b R = Me). The structures of intermediate compounds produced by addition of acid chloride across the imine bond and by partial hydrolyis of the resulting chlorine-containing compound have been determined. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码：15 / 19
页数：5
相关论文
共 50 条
12345