Dissolution of oxidation-cured poly(carbosilane) fiber into polar organic solvents

被引：0
|
作者：
Narisawa, M
Oda, S
Kitano, S
Okamura, K
机构：
来源：
JOURNAL OF APPLIED POLYMER SCIENCE | 1997年 / 65卷 / 02期
关键词：
poly(carbosilane); oxidation curing; ceramic precursor polymer; solubility;
D O I：
暂无
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The solubility of oxidation-cured polycarbosilane (PCS) fiber into benzene, tetrahydrofuran (THF), acetone, and ethanol was investigated. The solubility of the fiber in benzene and THF decreases as the curing temperature increases. The fiber cured at 433-463 K, however, shows higher solubility in acetone and ethanol than the original fiber and the fiber cured at 473 K. The remaining gels in benzene and THF keep their fibrous shape, while in acetone and ethanol often appear as swollen gels. (C) 1997 John Wiley & Sons, Inc.
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页码：261 / 265
页数：5
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  • [2] Improvement of chalcopyrite dissolution in acid media using polar organic solvents
    Solis-Marcial, O. J.
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  • [3] Dissolution of biomacromolecules in organic solvents by nano-complexing with poly(ethylene glycol)
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    LODESOVA, D
    LODES, A
    PIKLER, A
    [J]. CHEMICKE ZVESTI, 1978, 32 (02): : 166 - 174
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    HAGA, T
    [J]. JOURNAL OF POLYMER SCIENCE PART C-POLYMER LETTERS, 1982, 20 (12) : 629 - 634
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    [J]. JOURNAL OF APPLIED POLYMER SCIENCE, 2015, 132 (43)
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