Effect of household rice cooking on pesticide residues

被引:28
|
作者
Medina, Maria Belen [1 ,2 ]
Munitz, Martin Sebastian [1 ]
Resnik, Silvia Liliana [3 ,4 ,5 ]
机构
[1] Univ Natl Entre Rios, Fac Ciencias Alimentat, Concordia, Argentina
[2] Consejo Nacl Invest Cient & Tecn, Caba, Argentina
[3] Comis Invest Cient Prov Buenos Aires CIC, La Plata, Argentina
[4] Fdn Invest Cient Teresa Benedicta Cruz, Buenos Aires, DF, Argentina
[5] Univ Buenos Aires, Fac Ciencias Exactas & Nat, Caba, Argentina
关键词
Rice cooking methods; Pesticide distribution; Pesticide reduction; Mass balances; COOKED RICE; REMOVAL; RISK;
D O I
10.1016/j.foodchem.2020.128311
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
This investigation shows the pesticide distribution and reduction using three common household cooking methods. Extraction was performed using QuEChERS and solid phase microextraction methodologies for rice and water, respectively. Gas chromatography-mass spectrometry was used. Both methods showed good linearity (r(2) > 0.9996 and 0.9945), adequate recoveries (between 98.9 and 107.8% and 90.5-104.2%) and relative standard deviations lower than 4.5% and 7.0%, for rice and water, respectively. The initial concentration of deltamethrin, penconazole, kresoxim-methyl, cyproconazole, epoxiconazole and azoxystrobin, were 84.9, 242.2, 298.5, 230.7, 253.4 and 293.5 mu g/kg, respectively. Washing and soaking water reduce pesticides only 0.40 to 4.28%. The pesticide reduction during cooking were 20.73 to 57.72%, 32.74 to 70.39%, and 68.87 to 87.50% for traditional, excess water, and pre-soaking rice methods, respectively. Pre-soaking rice with extra water before cooking proved to be the method that generates the greatest reduction.
引用
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页数:8
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