Studies on the structural transformation of one-dimensional aluminophosphate chains

被引：0

作者：

Ding, H ^{[1
]}

Wang, KX ^{[1
]}

Yu, JH ^{[1
]}

Wang, C ^{[1
]}

Xu, RR ^{[1
]}

机构：

[1] Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130023, Peoples R China

来源：

CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2003年 / 19卷 / 01期

关键词：

aluminophosphates; structural transformation; rational synthesis; open-framework;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In the Al(i-PrO)(3)-H3PO4-en-EG system, two one-dimensional (ID) aluminophosphate chains AIPO-ESC and AlPO-CSC can transform to each other upon addition of some extra amount of en or H3PO4 to the reaction mixture. The transformation process has been studied by XRD and compositional analyses. Introducing Ni2+, cations, the ID AlPO-CSC chain which acts as BU can be successfully assembled to 3D open-framework NiAlP2O8. C2N2H9 (NiAPO-1) by connecting the terminal phosphonyl oxygens with Ni2+, species.

引用

页码：69 / 72

页数：4

共 16 条

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