Visible light-induced magnetization change of the cyano-bridged 3d-4f heterobimetallic

被引:25
|
作者
Li, GM
Sato, O
Akitsu, T
Einaga, Y
机构
[1] Keio Univ, Fac Sci & Technol, Dept Chem, Yokohama, Kanagawa 2238522, Japan
[2] Kanagawa Acad Sci & Technol, Special Res Lab Opt Sci, Kawasaki, Kanagawa 2130012, Japan
[3] Heilongjiang Univ, Sch Chem & Mat Sci, Harbin 150080, Peoples R China
关键词
light-induced; magnetism; cyano-bridge; 3d-4f complex;
D O I
10.1016/j.jssc.2004.06.015
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A visible light-induced magnetization change of the 3d-4f heterometallic, [Nd(DMF)(4)(H2O)(3)(mu-NC)Co(CN)(5)] (.) H2O (DNIF = N,N-dimethylformamide), is observed and described. The plots of (chiM) T versus T of the complex showed that the T values, after visible light illumination, were enhanced by about 25% as compared to before irradiation in the temperature range of 5-40 K. (C) 2004 Elsevier Inc. All rights reserved.
引用
收藏
页码:3835 / 3838
页数:4
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