A novel microporous cluster polymer {Et4N]2[WS4Cu4(CN)4]}n with cyanide-bridged three-dimensional open-framework

被引：4

作者：

Zhang, C

Jin, GC

Xu, Y

Fun, HK

Xin, XQ ^{[1
]}

机构：

[1] Nanjing Univ, Dept Chem, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China

[2] Univ Sains Malaysia, Sch Phys, Xray Crystallog Unit, George Town 11800, Malaysia

来源：

CHEMISTRY LETTERS | 2000年 / 05期

关键词：

D O I：

10.1246/cl.2000.502

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of (Et4N)(2)WS4 with CuCN (molar ratio of 1:4) in pyridine affords an interesting three-dimensional cluster polymer with open-framework. The crystal structure determination shows that the anionic WS4Cu4 units bridged by cyanide produce three-dimensional channels running down the crystallographic a axis.

引用

页码：502 / 503

页数：2

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