Electrochemical fluorination of N,N,N',N'-tetramethylethylenediamine

被引：9
|
作者：
Sartori, P
Velayutham, D
Ignatev, N
Noel, M
机构：
[1] CENT ELECTROCHEM RES INST,CSIR,KARAIKKUDI 623006,TAMIL NADU,INDIA
[2] NATL ACAD SCI UKRAINE,INST ORGAN CHEM,LAB ELECTROCHEM,UA-252660 KIEV,UKRAINE
来源：
JOURNAL OF FLUORINE CHEMISTRY | 1997年 / 83卷 / 01期
关键词：
electrochemical fluorination; N; N'; N'-tetramethylethylenediamine; perfluoro-N;
D O I：
10.1016/S0022-1139(97)00002-X
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The electrochemical fluorination of N,N,N',N'-tetramethylethylenediamine was carried out in a modified Simons type cell using anhydrous hydrogen fluoride as a solvent. Effects of various experimental parameters like concentration of amine, temperature, and current density etc. were investigated. In addition to perfluoro-N,N,N',N'-tetramethylethylenediamine, cyclic, cleavage, and partially fluorinated products were obtained and characterized by gas chromatography, IR spectroscopy, nuclear magnetic resonance and mass spectra. A plausible reaction pathway for the electrochemical fluorination of N,N,N',N'-tetramethylethylenediamine has been proposed based on the products obtained. (C) Elsevier Science S.A.
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页码：1 / 8
页数：8
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