Construction of homochiral alkaline-lanthanide heteronuclear helicates with Na+-selective bonding in the self-assembly process

被引：9

作者：

Li, Ge ^{[1
,2
]}

Wang, Li ^{[3
]}

Han, Qingxin ^{[4
]}

Liu, Weisheng ^{[1
,2
]}

机构：

[1] Lanzhou Univ, Coll Chem & Chem Engn, Key Lab Nonferrous Met Chem & Resources Utilizat, Lanzhou 730000, Gansu, Peoples R China

[2] Lanzhou Univ, Coll Chem & Chem Engn, State Key Lab Appl Organ Chem, Lanzhou 730000, Gansu, Peoples R China

[3] Xian Shiyou Univ, Coll Chem & Chem Engn, Xian 710065, Shaanxi, Peoples R China

[4] Shaanxi Univ Sci & Technol, Coll Bioresources Chem & Mat Engn, Xian 710021, Shaanxi, Peoples R China

来源：

DALTON TRANSACTIONS | 2019年 / 48卷 / 39期

关键词：

ORGANIC FRAMEWORK; EARTH-METALS; CHIRALITY; LUMINESCENT; SEPARATION; LIGANDS;

D O I：

10.1039/c9dt02483b

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A supramolecular approach to distinguish Na+ from other biologically important metal ions was demonstrated. By designing ligands reasonably, Na+-selective bonding was achieved in the construction of homochiral alkaline-lanthanide heteronuclear helicates, which was further confirmed by mixed-metal self-assembly experiments and H-1-NMR spectra.

引用

页码：14595 / 14599

页数：5