Room temperature oxidative desulfurization with MoO3 subnanoclusters supported on MCM-41

被引：17
|
作者：
Yang, Qianfan [1 ]
Wang, Jiasheng [1 ]
Wang, Wan-Hui [1 ]
Bao, Ming [1 ]
机构：
[1] Dalian Univ Technol, Sch Petr & Chem Engn, State Key Lab Fine Chem, Panjin 124221, Peoples R China
来源：
RSC ADVANCES | 2019年 / 9卷 / 37期
基金：
中国博士后科学基金; 中国国家自然科学基金;
关键词：
RAMAN-SPECTROSCOPY; MOLYBDENUM OXIDES; PART I; FUEL; CATALYST; OIL; DIBENZOTHIOPHENE;
D O I：
10.1039/c9ra03049b
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Subnano MoO3/MCM-41 was successfully prepared through doping (NH4)(6)Mo7O24 in the synthesis process of MCM-41. The morphology of MoO3/MCM-41 was visually observed by TEM and HADDF-STEM. N-2 sorption, XPS and Raman were further applied to investigate the structure of the material. MoO3/MCM-41 was used in the oxidative desulfurization process with tert-butyl hydroperoxide as oxidant. MoO3/MCM-41 showed outstanding catalytic activity and recycling ability at room temperature.
引用
收藏
页码：21473 / 21477
页数：5
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