Sulfated alumina aerogel-based superacid catalysts for 1-hexene oligomerization

被引：4
|
作者：
Lermontov, S. A. [1 ]
Yurkova, L. L. [1 ]
Straumal, E. A. [1 ]
Baranchikov, A. E. [2 ]
Shunina, I. G. [3 ]
Ivanov, V. K. [2 ]
机构：
[1] Russian Acad Sci, Inst Physiol Act Cpds, Severnyi Proezd 1, Chernogolovka 142432, Moscow Oblast, Russia
[2] Russian Acad Sci, Kurnakov Inst Gen & Inorgan Chem, Leninskii Pr 31, Moscow 119991, Russia
[3] Russian Acad Sci, Inst Problems Chem Phys, Pr Semenova 1, Chernogolovka 142432, Moscow Oblast, Russia
来源：
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2016年 / 61卷 / 01期
基金：
俄罗斯科学基金会;
关键词：
OXIDE AEROGEL; TEMPERATURE; ZIRCONIA; TITANIA; ACIDITY; SUPPORT;
D O I：
10.1134/S0036023616010137
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Al2O3 aerogel samples were synthesized by supercritical drying in two different media: isopropanol and methyl tert-butyl ether. After sulfation in a SO2Cl2 vapor, the aerogel acquired superacid properties (-12.4 a parts per thousand currency sign H (0) a parts per thousand currency signaEuro"11.99) and efficiently catalyzed 1-hexene oligomerization and dimerization.
引用
收藏
页码：7 / 10
页数：4
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