Photoluminescence properties of Eu2+ and Mn2+-activated BaMgP2O7 as a potential red phosphor for white-emission

A phosphate compound, BaMgP2O7 was co-doped with Eu2+ and Mn2+ for making a red-emitting phosphor. The phosphor was prepared by a solid-state reaction at high temperature. The photoluminescence properties were investigated under ultraviolet (UV) ray excitation. From a powder X-ray diffraction (XRD) analysis, the formation of single-phased BaMgP2O7 with a monoclinic structure was confirmed. In the photoluminescence spectra, the BaMgP2O7:Eu,Mn phosphor emits two distinctive colors: a blue band centered at 409 nm originating from Eu2+ and a red band at 615 nm caused by Mn2+. Also, efficient energy transfer from Eu2+ to Mn2+ in the BaMgP2O7:Eu,Mn system was verified by observing that the excitation spectra of BaMgP2O7:Eu,Mn emitted at 409 and 615 nm by Eu2+ emission and Mn2+ emission, respectively, are almost the same as that of BaMgP2O7:Eu monitored at 409 nm. The optimum concentration of Eu2+ ions in BaMgP2O7:0.015 Eu excited at 309 nm wavelength is 1.5 mol%. With an increase of Mn2+ content up to 17.5 mol%, a systematic decline in the intensity of the excitation spectrum by Eu2+ and a gradual growth in the intensity of emission band by Mn2+ were observed. Accordingly, the optimum concentration of Mn2+ in BaMgP2O7:0.015Eu,Mn is 17.5 mol%. The maximum spectral overlap between emission of Eu2+ and excitation of Mn2+ is achieved in a composition of BaMgP2O7:0-015Eu,0.175Mn, resulting in considerable red-emission at 615 nm. (C) 2009 Elsevier B.V. All rights reserved.