Photoreduction of Prussian Blue Intercalated into Titania Nanosheet Ultrathin Films

被引:43
|
作者
Yamamoto, Takashi [1 ]
Saso, Naoki [1 ]
Umemura, Yasushi [2 ]
Einaga, Yasuaki [1 ]
机构
[1] Keio Univ, Dept Chem, Yokohama, Kanagawa 2238522, Japan
[2] Natl Def Acad, Dept Appl Chem, Yokosuka, Kanagawa 2368689, Japan
关键词
LANGMUIR-BLODGETT-FILMS; PHOTOINDUCED MAGNETIZATION;
D O I
10.1021/ja9041274
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Ultrathin fims composed of titania nanosheets and Prussian Blue were prepared by using the modified Langmuir-Blodgett technique. The ultrathin films could be deposited in a layer-by-layer manner with lamellar structure. Upon band gap excitation of titania nanosheets, the generated electrons were injected into ferromagnetic Prussian Blue, resulting in reduction to paramagnetic Prussian White. It was revealed that the reaction could proceed only in the presence of hole-scavenging interlayer water molecules.
引用
收藏
页码:13196 / 13197
页数:2
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