Stereochemistry of the intramolecular carbolithiation of vinyl sulfides

被引：18
|
作者：
Hoffmann, RW [1 ]
Koberstein, R [1 ]
Remacle, B [1 ]
Krief, A [1 ]
机构：
[1] FAC UNIV NOTRE DAME PAIX,DEPT CHEM,B-5000 NAMUR,BELGIUM
来源：
CHEMICAL COMMUNICATIONS | 1997年 / 22期
关键词：
D O I：
10.1039/a705799g
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Intramolecular carbolithiation of vinyl sulfides to generate configurationally stable alpha-durylthioalkyllithium compounds at -105 degrees C in THF showed carbolithiation to be nonstereospecific regarding the newly formed lithium bearing stereocentre.
引用
收藏
页码：2189 / 2190
页数：2
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