Removal of dibenzothiophene in diesel oil by oxidation over a promoted activated carbon catalyst

被引：20

作者：

Zhou, X. L. ^{[1
]}

Tan, Q. ^{[1
]}

Yu, G. X. ^{[2
]}

Chen, L. F.

Wang, J. A. ^{[3
]}

Novaro, O. ^{[4
]}

机构：

[1] E China Univ Sci & Technol, Sch Chem Engn, Shanghai 200237, Peoples R China

[2] Jianghan Univ, Sch Chem & Environm Engn, Wuhan 430056, Peoples R China

[3] Inst Politecn Nacl, ESIQIE, Lab Catalisis & Mat, Mexico City 07738, DF, Mexico

[4] Univ Nacl Autonoma Mexico, Inst Fis, Mexico City 01000, DF, Mexico

来源：

KINETICS AND CATALYSIS | 2009年 / 50卷 / 04期

关键词：

WET AIR OXIDATION; HYDROGEN-PEROXIDE; SELECTIVE OXIDATION; SULFUR-COMPOUNDS; ORGANIC SULFUR; FUEL-OIL; DESULFURIZATION; DECOMPOSITION; RADICALS; H2O2;

D O I：

10.1134/S0023158409040119

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Oxidative removal of dibenzothiophene (DBT) in n-octane solution by H2O2 on a promoted activated carbon (AC) catalyst was studied. DBT adsorption and catalytic behaviors on AC were examined. Effects of pH in aqueous phase, amounts of AC and formic acid (HCOOH) for promotion as well as initial molar H2O2/S ratio were investigated. Experimental results led to conclusion that DBT was readily oxidized by H2O2 over an AC catalyst promoted by HCOOH. Suitable amount of AC can improve the activity of H2O2 resulting in a deeper extent of sulfur removal. A 100% conversion of DBT in an octane solution by H2O2 oxidation was attained on the HCOOH-H2O2/AC catalyst at 80A degrees C for a reaction time of 30 min.

引用

页码：543 / 549

页数：7

共 50 条

[1] Removal of dibenzothiophene in diesel oil by oxidation over a promoted activated carbon catalyst
X. L. Zhou
Q. Tan
G. X. Yu
L. F. Chen
J. A. Wang
O. Novaro
[J]. Kinetics and Catalysis, 2009, 50 : 543 - 549
[2] Hydrotreatment of vegetable oil for green diesel over activated carbon supported molybdenum carbide catalyst
Wang, Fei
Xu, Junming
Jiang, Jianchun
Liu, Peng
Li, Fanglin
Ye, Jun
Zhou, Minghao
[J]. FUEL, 2018, 216 : 738 - 746
[3] Synthesis, Characterization, and Evaluation of Activated Carbon Spheres for Removal of Dibenzothiophene from Model Diesel Fuel
Zhang, Changming
Song, Wen
Sun, Guohua
Xie, Lijing
Wan, Liu
Wang, Jianlong
Li, Kaixi
[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2014, 53 (11) : 4271 - 4276
[4] Cu-promoted Pt/activated carbon catalyst for glycerol oxidation to lactic acid
Zhang, Chen
Wang, Tao
Liu, Xiao
Ding, Yunjie
[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2016, 424 : 91 - 97
[5] Kinetics of the wet oxidation of phenol over an Fe/activated carbon catalyst
Quintanilla, A.
Casas, J. A.
Rodriguez, J. J.
Kreutzer, M. T.
Kapteijn, Freek
Moulijn, J. A.
[J]. INTERNATIONAL JOURNAL OF CHEMICAL REACTOR ENGINEERING, 2007, 5
[6] OXIDATION OF PROPANE OVER A DIESEL EXHAUST CATALYST
WANKE, SE
[J]. CANADIAN JOURNAL OF CHEMICAL ENGINEERING, 1973, 51 (04): : 454 - 458
[7] Selective Deoxygenation of Sludge Palm Oil into Diesel Range Fuel over Mn-Mo Supported on Activated Carbon Catalyst
Alsultan, Abdulkareem
Asikin-Mijan, Nurul
Obeas, Laith
Islam, Aminul
Mansir, Nasar
Teo, Siow
Razali, Siti
Nassar, Maadh
Mohamad, Surahim
Taufiq-Yap, Yun
[J]. CATALYSTS, 2022, 12 (05)
[8] Selective removal of dibenzothiophene from commercial diesel using manganese dioxide-modified activated carbon: a kinetic study
Abu Safieh, Kayed A.
Al-Degs, Yahya S.
Sunjuk, Mahmoud S.
Saleh, Abdullah I.
Al-Ghouti, Mohammad A.
[J]. ENVIRONMENTAL TECHNOLOGY, 2015, 36 (01) : 98 - 105
[9] ZnO-Activated Carbon Blended as a Catalyst for Oxidative Desulfurization of Dibenzothiophene
Trisunaryanti, Wega
Sumbogo, Satriyo Dibyo
Novianti, Safa Annissa
Fatmawati, Dyah Ayu
Ulfa, Maria
Nikmah, Yatim Lailun
[J]. BULLETIN OF CHEMICAL REACTION ENGINEERING AND CATALYSIS, 2021, 16 (04): : 881 - 887
[10] Modified activated carbon as catalyst for NO oxidation
Sousa, Juliana P. S.
Pereira, Manuel F. R.
Figueiredo, Jose L.
[J]. FUEL PROCESSING TECHNOLOGY, 2013, 106 : 727 - 733

← 1 2 3 4 5 →