Fullerene acting as an electron donor in a donor-acceptor dyad to attain the long-lived charge-separated state by complexation with scandium ion

被引：27
|
作者：
Ohkubo, Kei
Ortiz, Javier
Martin-Gomis, Luis
Fernandez-Lazaro, Fernando
Sastre-Santos, Angela [1 ]
Fukuzumi, Shunichi
机构：
[1] Univ Miguel Hernandez, Inst Bioingn, Div Quim Organ, Elche 03202, Spain
[2] Osaka Univ, SORST, Japan Sci & Technol Agcy JST, Grad Sch Engn,Dept Mat & Life Sci, Suita, Osaka 5650871, Japan
来源：
CHEMICAL COMMUNICATIONS | 2007年 / 06期
关键词：
D O I：
10.1039/b612613h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A long-lived charge-separated (CS) state of fullerene-trinitro-fluorenone linked dyad in which fullerene acts as an electron donor is formed by photoinduced electron transfer from C-60 to TNF in the presence of Sc(OTf)(3); the CS lifetime is determined as 23 ms in PhCN at 298 K.
引用
收藏
页码：589 / 591
页数：3
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