Process metallurgical evaluation and application of very fine bubbling technology

The potential of VFB(very fine bubbling)-technology in steelmaking, developed for the production of super clean steels, was investigated. Recent R&D work has proven that with very fine argon bubbling through a developed special porous plug (SPP) at low flow rates, the total oxygen content of low carbon steel grades can be lowered to a level of 6 ppm under industrial vacuum conditions [1; 2] and to a level of 10 ppm under argon protective atmosphere [2]. The perspective of industrial application of the VFB technology to a 56-t ladle furnace of Helliniki Halyvourgia S.A., Greece, in order to improve steel cleanliness, requires additional R&D efforts. It is important to define the limits of VFB technology in respect of alloys dissolution, mixing time and homogenisation of steel and slag/metal reactions. In this work, a gas driven bubble aqueous reactor model simulating the bottom gas stirred ladle by means of gas injection through a SPP and a conventional porous plug was studied. Various operating conditions as well as different positions for the porous plug with and without a top oil layer were simulated. Tests concerning mixing time, solid-liquid mass transfer and critical gas flow rate, liquid/liquid mass transfer, using the SPP and a conventional porous plug have been performed. The evaluation of experimental results delivered important information for the design and operation of steel ladles, applying VFB-technology. Experimental results with SPP bubbles' agitated steel (1600 degreesC) in laboratory and technical scale experiments in IF and VIF are presented and discussed.