A Substituent Effect on Two-Photon Absorption of Diphenylacetylene Derivatives with an Electron-Donating/Withdrawing Group

被引：6
|
作者：
Ishii, Tetsuro [1 ]
Isozaki, Tasuku [1 ,2 ]
Kinoshita, Sho [1 ]
Takeuchi, Ryo [1 ]
Kashihara, Wataru [1 ]
Suzuki, Tadashi [1 ]
机构：
[1] Aoyama Gakuin Univ, Dept Chem & Biol Sci, Sagamihara, Kanagawa 2525258, Japan
[2] JF Oberlin Univ, Coll Arts & Sci, Div Nat Sci, Tokyo 1940294, Japan
来源：
JOURNAL OF PHYSICAL CHEMISTRY A | 2021年 / 125卷 / 08期
关键词：
DESIGN; NANOPARTICLES; MOLECULES;
D O I：
10.1021/acs.jpca.0c10545
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Two-photon absorption for diphenylacetylene derivatives with an electron-donating (ED) or electron-withdrawing (EW) group (DPA-Rs) was investigated by high-sensitivity optical-probing photoacoustic spectroscopy. Two-photon absorption spectra and two-photon absorption cross sections 6 (2) for DPA-Rs were successfully obtained. Two-photon absorption spectra of DPA-Rs with stronger ED or EW groups display more significant red-shifts and larger 6 (2) values. Simulated two-photon absorption spectra, using time-dependent density functional theory within the Tamm-Dancoff approximation, compared well with the experimental spectra. Based on the three-state model, the substituent effect on the two-photon absorption for DPA-Rs was expected to manifest in the transition dipole moments and detuning energies. Information obtained from investigating the monosubstituent effect on two-photon absorption of DPA is critical for an improved understanding of two-photon absorption.
引用
收藏
页码：1688 / 1695
页数：8
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