Combustion synthesis of CuO-ZnO-ZrO2 catalysts for the hydrogenation of carbon dioxide to methanol

被引：112

作者：

Guo, Xiaoming ^{[1
,2
]}

Mao, Dongsen ^{[1
]}

Wang, Song ^{[1
,2
]}

Wu, Guisheng ^{[1
]}

Lu, Guanzhong ^{[1
,2
]}

机构：

[1] Shanghai Inst Technol, Res Inst Appl Catalysis, Dept Chem Engn, Shanghai 200235, Peoples R China

[2] E China Univ Sci & Technol, Res Inst Ind Catalysis, Shanghai 200237, Peoples R China

来源：

CATALYSIS COMMUNICATIONS | 2009年 / 10卷 / 13期

关键词：

CuO-ZnO-ZrO2; catalyst; Combustion synthesis; Urea/nitrate ratio; CO2; hydrogenation; Methanol; CO2; HYDROGENATION; CU-ZNO/ZRO2; CATALYSTS; CU/ZNO/ZRO2; SOLID-SOLUTIONS; ZIRCONIA; POWDERS; ADDITIVES; STATE; H-2; CU;

D O I：

10.1016/j.catcom.2009.05.004

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Various CuO-ZnO-ZrO2 (CZZ) catalysts have been synthesized by urea-nitrate combustion method and their performances for methanol synthesis from CO2 hydrogenation have been investigated. The effects Of urea/nitrate ratio on physicochemical and catalytic properties were studied by XRD, BET, H-2-TPR and reactive N2O adsorption techniques. The results show that when 50% of stoichiometric amount of urea was used, the CZZ catalyst exhibited an optimum catalytic behavior. The combustion method was found to be a simple, fast and valuable route for the preparation of CZZ catalyst for methanol synthesis from CO2 hydrogenation. (C) 2009 Elsevier B.V. All rights reserved.

引用

页码：1661 / 1664

页数：4

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