Reinvestigation of the binary diagram Na3PO4-FePO4 and crystal structure of a new iron phosphate Na3Fe3(PO4)4

被引：29
|
作者：
Lajmi, B
Hidouri, M
Rzeigui, M
Ben Amara, M [1 ]
机构：
[1] Fac Sci Monastir, Dept Chim, Lab Chim Struct Mat, Monastir 5000, Tunisia
[2] Fac Sci Bizerte, Dept Chim, Jarzouna 7021, Tunisia
来源：
MATERIALS RESEARCH BULLETIN | 2002年 / 37卷 / 15期
关键词：
inorganic compounds; layered compound; X-ray diffraction; thermal analysis; crystal structure;
D O I：
10.1016/S0025-5408(02)00940-6
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
A new iron(III) phosphate Na3Fe3(PO4)(4) has been synthesized and characterized. It decomposes before melting at 860degreesC into FePO4 and Na3Fe2(PO4)(3). The structure of the compound was determined by single-crystal X-ray diffraction. The unit cell is monoclinic with the following parameters: a = 19.601(8) Angstrom, b = 6.387(1) Angstrom, c = 10.575(6) Angstrom and beta = 91.81(4)degrees; Z = 4; space group: C2/c. Na3Fe3(PO4)(4) exhibits a layered structure involving corner-linkage between FeO6 octahedra, and corner- and edge-sharing between FeO6 octahedra and PO4 tetrahedra. The Na+ cations occupying the interlayer space are six and seven-fold coordinated by oxygen atoms. The relationship between the structure of Na3Fe3(PO4)(4) and the previous reported hydrate K3Fe3(PO4)(4)H2O will be discussed. (C) 2002 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：2407 / 2416
页数：10
相关论文
共 50 条
  • [1] NA3PO4-FEPO4 PHASE-DIAGRAM
    LAZORYAK, BI
    ORALKOV, SY
    AZIEV, RG
    ZHURNAL NEORGANICHESKOI KHIMII, 1988, 33 (02): : 453 - 456
  • [2] Revisiting the layered Na3Fe3(PO4)4 phosphate sodium insertion compound: structure, magnetic and electrochemical study
    Shinde, Ganesh S.
    Gond, Ritambhara
    Avdeev, Maxim
    Ling, Chris D.
    Rao, Rayavarapu Prasada
    Adams, Stefan
    Barpanda, Prabeer
    MATERIALS RESEARCH EXPRESS, 2020, 7 (01)
  • [3] Crystal structure of the new titanium phosphate Na3CaTi(PO4)3
    Krimi, S.
    El Jazouli, A.
    Lachgar, A.
    ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2007, 63 : S291 - S292
  • [4] Study of a Layered Iron(III) Phosphate Phase Na3Fe3(PO4)4 Used as Positive Electrode in Lithium Batteries
    Trad, Khiem
    Carlier, Dany
    Wattiaux, Alain
    Ben Amara, Mongi
    Delmas, Claude
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2010, 157 (08) : A947 - A952
  • [5] A Layered Iron(III) Phosphate Phase, Na3Fe3(PO4)4: Synthesis, Structure, and Electrochemical Properties as Positive Electrode in Sodium Batteries
    Trad, Khiem
    Carlier, Dan
    Croguennec, Laurence
    Wattiaux, Main
    Lajmi, Besma
    Ben Amara, Mongi
    Delmas, Claude
    JOURNAL OF PHYSICAL CHEMISTRY C, 2010, 114 (21): : 10034 - 10044
  • [6] SOLID ELECTROLYTES BASED ON NA3PO4-ZR-4+, NA3PO4-HF-4+, NA3PO4-TI-4+, NA3PO4-SN-4+, NA3PO4-CE-4+, NA3PO4-TH-4+
    IRVINE, JTS
    WEST, AR
    JOURNAL OF SOLID STATE CHEMISTRY, 1988, 74 (02) : 385 - 392
  • [7] STRUCTURAL AND THERMAL-PROPERTIES OF THE PHOSPHATE, NA3EU(PO4)2 .1. A STUDY OF NA3PO4-EUPO4 AND NA3EU(PO4)2-NA3GD(PO4)2 SYSTEMS
    CHAO, ZJ
    PARENT, C
    LEFLEM, G
    HAGENMULLER, P
    JOURNAL OF SOLID STATE CHEMISTRY, 1989, 82 (02) : 255 - 263
  • [8] Crystal structures and magnetic properties of iron (III)-based phosphates Na4NiFe(PO4)3 and Na2Ni2Fe(PO4)3
    Essehli, Rachid
    El Bali, Brahim
    Benmokhtar, Said
    Bouziane, Khalid
    Manoun, Bouchaib
    Abdalslam, Mouner Ahmed
    Ehrenberg, Helmut
    JOURNAL OF ALLOYS AND COMPOUNDS, 2011, 509 (04) : 1163 - 1171
  • [9] Crystal Structure of Na3MgTi(PO4)3.
    Krimi, Saida
    El Jazouli, Abdelaziz
    Lachgar, E. T. A.
    ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2009, 65 : S199 - S199
  • [10] TERNARY PHOSPHATES IN THE SYSTEMS CA3(PO4)2-NA3ND(PO4)2, CA3(PO4)2-NA3U(PO4)2, CA3(PO4)2-NA3ER(PO4)2
    LAZORYAK, BI
    IVANOV, LN
    STRUNENKOVA, TV
    GOLUBEV, VN
    VITING, BN
    INORGANIC MATERIALS, 1990, 26 (02) : 283 - 286
12345