magnetic order;
rare-earth metals;
Rietveld refinement;
D O I:
10.1016/S0921-4526(96)01076-9
中图分类号:
O469 [凝聚态物理学];
学科分类号:
070205 ;
摘要:
The crystal and magnetic structures of RCuGe (R = Pr, Nd, Tb, Dy, Ho and Er) compounds were determined by neutron diffraction on polycrystalline samples. Their magnetic data along with those for GdCuGe are reported. The compounds with R = Pr and Nd have the hexagonal AIB(2)-type crystal structure, while other compounds represent hexagonsal LiGeGa-type. All compounds are antiferromagnetic at low temperatures. The Neel temperatures changes from 1.8 K for R = 17 K for R = Gd. The magnetic structure of these compounds is sine modulated with the wave vector k = [1/3, 0, 0] (except NdCuGe in case of which k = [1/2, 0, 0]). For heavy lanthanided compounds, the change of direction of the magnetic moments from the one perpendicular to the c-axis (R = Tb and Dy) to the one parallel (R = Ho and Er) has been found. For ErCuGe, the change of magnetic structure is observed at low temperatures.