A new catalytic route for the activation of sp-hybridized carbon-hydrogen bonds

被引：35

作者：

Marciniec, Bogdan ^{[1
]}

Dudziec, Beata ^{[1
]}

Kownacki, Ireneusz ^{[1
]}

机构：

[1] Adam Mickiewicz Univ, Fac Chem, Dept Organomet Chem, PL-60780 Poznan, Poland

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 48期

关键词：

alkynes; C-H activation; homogeneous catalysis; ruthenium; silanes;

D O I：

10.1002/anie.200603582

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Vinyl-substituted silicon compounds react selectively with terminal alkynes in the presence of complexes containing [Ru]-H and [Ru]-Si bonds to form functionalized silylethynes (see picture). This reaction opens up a new catalytic route for the preparation of a class of potent organosilicon reagents for organic synthesis. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：8180 / 8184

页数：5

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