STRUCTURE AND WATER RELATIONS OF MELANOIDINS INVESTIGATED BY THERMAL, RHEOLOGICAL, AND MICROSCOPIC ANALYSIS

被引:5
|
作者
Venir, Elena [1 ]
Pittia, Paola [2 ]
Giavon, Sonia [1 ]
Maltini, Enrico [1 ]
机构
[1] Univ Teramo, Dept Food Sci, I-64023 Mosciano Sant Angelo, TE, Italy
[2] Univ Udine, Dept Food Sci, I-33100 Udine, Italy
关键词
Melanoidins; Adsorption isotherm; Intrinsic viscosity; Glass transition; Rheology; Structure; DILUTE-SOLUTION PROPERTIES; GLASS-TRANSITION; SORPTION ISOTHERMS; MAILLARD REACTION; PHYSICAL CHANGES; FOOD; MODEL; POLYSACCHARIDES; VISCOSITY; RATES;
D O I
10.1080/10942910802078469
中图分类号
TS2 [食品工业];
学科分类号
0832 ;
摘要
Water soluble melanoidins (WSM) from a glucose-glycine model system were obtained and separated into high (HMW) and low (LMW) molecular weight fractions. Adsorption isotherm and GAB and BET fitting parameters of WSM were determined. Physical and structural properties were investigated through thermal and rheological analysis. The LMW fraction exhibited thermal properties similar to that of oligosaccharides and the HMW fraction was compatible with a complex and large molecular size biopolymer structure, while both exhibited gel like properties. Intrinsic viscosity values were consistent with spherical hydrodynamic volumes.
引用
收藏
页码:819 / 833
页数:15
相关论文
共 50 条
  • [1] Rheological and thermal analysis of bentonites for water base drilling fluids
    Kok, MV
    ENERGY SOURCES, 2004, 26 (02): : 145 - 151
  • [2] A rheological modelling and microscopic analysis of bigels
    Lupi, Francesca R.
    De Santo, Maria P.
    Ciuchi, Federica
    Baldino, Noemi
    Gabriele, Domenico
    RHEOLOGICA ACTA, 2017, 56 (09) : 753 - 763
  • [3] A rheological modelling and microscopic analysis of bigels
    Francesca R. Lupi
    Maria P. De Santo
    Federica Ciuchi
    Noemi Baldino
    Domenico Gabriele
    Rheologica Acta, 2017, 56 : 753 - 763
  • [4] Thermal, microscopic, and rheological characterization of rejuvenated asphalt binders
    Amal Abdelaziz
    Eyad Masad
    Amy Epps Martin
    Edith Arámbula-Mercado
    Akash Bajaj
    Materials and Structures, 2022, 55
  • [5] Thermal, microscopic, and rheological characterization of rejuvenated asphalt binders
    Abdelaziz, Amal
    Masad, Eyad
    Martin, Amy Epps
    Arambula-Mercado, Edith
    Bajaj, Akash
    MATERIALS AND STRUCTURES, 2022, 55 (03)
  • [6] Insights into the microscopic behaviour of nanoconfined water: host structure and thermal effects
    Gomez-Alvarez, P.
    Calero, S.
    CRYSTENGCOMM, 2015, 17 (02): : 412 - 421
  • [7] On the microscopic structure of liquid water
    Perera, Aurelien
    MOLECULAR PHYSICS, 2011, 109 (20) : 2433 - 2441
  • [8] Microscopic Insight into Surface Wetting: Relations between Interfacial Water Structure and the Underlying Lattice Constant
    Zhu, Chongqin
    Li, Hui
    Huang, Yongfeng
    Zeng, Xiao Cheng
    Meng, Sheng
    PHYSICAL REVIEW LETTERS, 2013, 110 (12)
  • [9] Processes of dehydration and rehydration of raffinose pentahydrate investigated by thermal analysis and FT-IR/DSC microscopic system
    Cheng, Wen-Ting
    Lin, Shan-Yang
    CARBOHYDRATE POLYMERS, 2006, 64 (02) : 212 - 217
  • [10] Microscopic structure of water in a water/oil emulsion
    Mancinelli, R.
    Bruni, F.
    Ricci, M. A.
    Imberti, S.
    JOURNAL OF CHEMICAL PHYSICS, 2013, 138 (20):