Pd/P(i-BuNCH2CH2)3N:: an efficient catalyst for Suzuki cross-coupling of aryl bromides and chlorides with arylboronic acids

被引：82

作者：

Urgaonkar, S ^{[1
]}

Nagarajan, M ^{[1
]}

Verkade, JG ^{[1
]}

机构：

[1] Iowa State Univ, Dept Chem, Ames, IA 50011 USA

来源：

TETRAHEDRON LETTERS | 2002年 / 43卷 / 49期

基金：

美国国家科学基金会;

关键词：

cross-coupling reaction; ligands; bicyclic triaminophosphine;

D O I：

10.1016/S0040-4039(02)02189-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Pd(OAc)(2) in combination with the commercially available ligand P(i-BuNCH2CH2)(3)N catalyzes the Suzuki cross-coupling reaction of a wide variety of aryl bromides and chlorides with arylboronic acids, affording the desired biaryls in excellent yields. It has also been shown that P(NMe2)(3) can be employed as a ligand, though with significantly more limited success. (C) 2002 Elsevier Science Ltd. All rights reserved.

引用

页码：8921 / 8924

页数：4

共 50 条

[1] P(i-BuNCH2CH2)3N:: An efficient ligand for the direct α-arylation of nitriles with aryl bromides
You, JS
Verkade, JG
JOURNAL OF ORGANIC CHEMISTRY, 2003, 68 (21): : 8003 - 8007
[2] Pd2(dba)3/P(i-BuNCH2CH2)3N-catalyzed Stille cross-coupling of aryl chlorides
Su, WP
Urgaonkar, S
Verkade, JG
ORGANIC LETTERS, 2004, 6 (09) : 1421 - 1424
[3] Pd2(dba)3/(t-Bu)2PN=P(i-BuNCH2CH2)3N Catalyzed Stille cross-couplings of aryl and hetero aryl bromides and chlorides
Chintareddy, Venkat Reddy
Verkade, John G.
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2010, 239
[4] Pd2(dba)3/(t-Bu)2PN=P(i-BuNCH2CH2)3N Catalyzed Kumada cross-couplings of aryl bromides and chlorides
Chintareddy, Venkat Reddy
Verkade, John G.
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2010, 239
[5] P(i-BuNCH2CH2)3N:: An effective ligand in the palladium-catalyzed amination of aryl bromides and iodides
Urgaonkar, S
Nagarajan, M
Verkade, JG
JOURNAL OF ORGANIC CHEMISTRY, 2003, 68 (02): : 452 - 459
[6] A convenient palladium/ligand catalyst for Suzuki cross-coupling reactions of arylboronic acids and aryl chlorides
Bei, XH
Crevier, T
Guram, AS
Jandeleit, B
Powers, TS
Turner, HW
Uno, T
Weinberg, WH
TETRAHEDRON LETTERS, 1999, 40 (20) : 3855 - 3858
[7] P(i-BuNCH2CH2)3N:: an efficient promoter for the microwave synthesis of diaryl ethers
Raders, Steven M.
Verkade, John G.
TETRAHEDRON LETTERS, 2008, 49 (21) : 3507 - 3511
[8] (t-Bu)2PN=P(i-BuNCH2CH2)3N: New efficient ligand for palladium-assisted C-N couplings of aryl bromides and chlorides, and for vinyl bromides at room temperature
Reddy, Venkat Reddy Chinta
Kingston, Jesudoss V.
Verkade, John G.
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2007, 233 : 568 - 568
[9] P(i-BuNCH2CH2)3N:: An efficient promoter for the nucleophilic aromatic substitution reaction of aryl fluorides with aryl TBDMS (or TMS) ethers
Urgaonkar, S
Verkade, JG
ORGANIC LETTERS, 2005, 7 (15) : 3319 - 3322
[10] Indazolium halides as efficient ligands for Pd-catalyzed Suzuki-Miyaura cross-coupling of aryl bromides with arylboronic acids
Chen, Qian
Mao, Zhuqing
Guo, Fang
Liu, Xiaoshuang
TETRAHEDRON LETTERS, 2016, 57 (33) : 3735 - 3738

← 1 2 3 4 5 →