A Supported Ni Catalyst Produced from Ni-Al Hydrotalcite-Like Precursor for Reduction of Furfuryl Alcohol to Tetrahydrofurfuryl Alcohol by NaBH4 in Water

被引：4
|
作者：
Ren, Dezhang [1 ]
Wang, Jingyi [1 ]
Jiang, Xuelei [1 ]
Song, Zhiyuan [2 ]
Norinaga, Koyo [3 ]
Huo, Zhibao [1 ,2 ]
机构：
[1] Shanghai Ocean Univ, Coll Marine Ecol & Environm, 1999 Huchenghuan Rd, Shanghai 201306, Peoples R China
[2] Shanghai Jiao Tong Univ, Sch Environm Sci & Engn, 800 Dongchuan Rd, Shanghai 200240, Peoples R China
[3] Nagoya Univ, Dept Chem Syst Engn, Grad Sch Engn, Chikusa Ku, Furo Cho, Nagoya, Aichi 4648603, Japan
来源：
CHEMISTRYSELECT | 2021年 / 6卷 / 04期
关键词：
Furfuryl alcohol; heterogeneous catalysis; hydrogenation; Nickel; Aluminum hydrotalcite compounds; tetrahydrofurfuryl alcohol; LAYERED DOUBLE OXIDES; SELECTIVE HYDROGENATION; TEMPERATURE HYDROGENATION; PHASE HYDROGENATION; CONVERSION; BIOMASS; NANOPARTICLES; OXIDATION; REMOVAL; ESTERS;
D O I：
10.1002/slct.202003543
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Tetrahydrofurfuryl alcohol (THFA) is a kind of high value-added compound in industry, which can be obtained from biomass chemical engineering. However, Synthesis of THFA under mild condition with green hydrogen donors remains a big challenge. In this article, a supported Ni catalyst derived from Ni-Al hydrotalcite-like compounds (HTs) as precursors for the reduction of furfuryl alcohol (FA) into THFA with NaBH4 as reducing agent in water was first reported. As a result, Ni/Al2O3-HT exhibited high catalytic activity for the transformation, and THFA was achieved in 100 % yield at 60 degrees C for 60 min. Moreover, Ni/Al2O3-HT could be recycled at least seven times without the loss of its activity. Under optimized conditions, the reduction reaction of several furan and ketone compounds was investigated. A possible mechanism for the reduction of FA to afford THFA was also proposed.
引用
收藏
页码：551 / 556
页数：6
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