Applications of the [2,3]-Wittig rearrangement to total synthesis

被引：13
|
作者：
McGowan, G [1 ]
机构：
[1] Univ Manchester, Dept Chem, Manchester M13 9PL, Lancs, England
来源：
AUSTRALIAN JOURNAL OF CHEMISTRY | 2002年 / 55卷 / 12期
关键词：
D O I：
10.1071/CH02184
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The applications of [2,3]-Wittig rearrangement to total synthesis were analyzed. The [2,3]-Wittig rearrangement is a thermally allowed sigmatropic isomerization, initiated by the treatment of allylic ethers with suitable base. To introduce chirality into achiral molecules, a method was proposed known as asymmetric metallation which is deprotonation with a chiral non-racemic base.
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收藏
页码：799 / 799
页数：1
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