tert-Butyl N-[1-diazoacetyl-3-(methylsulfanyl)propyl]carbamate

被引：0
|
作者：
Mehmood, Tahir [1 ]
Zaidi, Javid H. [1 ]
Jones, Peter G. [2 ]
机构：
[1] Quaid I Azam Univ, Dept Chem, Islamabad 45320, Pakistan
[2] Tech Univ Carolo Wilhelmina Braunschweig, Inst Anorgan & Analyt Chem, D-38106 Braunschweig, Germany
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2009年 / 65卷
关键词：
D O I：
10.1107/S1600536809030815
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the enantiomerically pure title compound, C11H19N3O3S, the chain C-N-C(O)-O-C-C (from the asymmetric carbon to a methyl of the tert-butyl group) displays an extended conformation. In the crystal, molecules are linked into chains parallel to the c axis by classical N-H center dot center dot center dot O-diazocarbonyl hydrogen bonding and an unusual intermolecular three-centre interaction involving the amino acid (aa) carbonyl O-aa and the diazocarbonyl grouping C(O)-CH-N equivalent to N, with H center dot center dot center dot O-aa = 2.51 angstrom and N center dot center dot center dot O-aa = 2.8141 (14) angstrom.
引用
收藏
页码：O2120 / U1746
页数：11
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