Excited-state absorption of mono-, di- and tri-nuclear cyclometalated platinum 4,6-diphenyl-2,2′-bipyridyl complexes

被引：15
|
作者：
Li, Yunjing [1 ]
Pritchett, Timothy M. [2 ]
Shao, Pin [1 ]
Haley, Joy E. [3 ,4 ]
Zhu, Hongjun [1 ]
Sun, Wenfang [1 ]
机构：
[1] N Dakota State Univ, Dept Chem & Mol Biol, Fargo, ND 58108 USA
[2] USA, Res Lab, AMSRD ARL SE EM, Adelphi, MD 20783 USA
[3] USAF, Res Lab, Mat & Mfg Directorate, Wright Patterson AFB, OH 45433 USA
[4] Universal Energy Syst Inc, Dayton, OH 45432 USA
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2009年 / 694卷 / 23期
关键词：
Triplet excited-state absorption cross-section; Singlet excited-state absorption cross-section; Excited-state lifetime; Triplet quantum yield; Cyclometalated platinum(II) 4,6-diphenyl-2,2 '-bipyridyl complexes; Z-scan; PHOTOPHYSICS;
D O I：
10.1016/j.jorganchem.2009.07.045
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The ground-state absorption cross-sections (sigma(g)), triplet excited-state absorption cross-section (sigma(T)) at 532 nm, singlet excited-state absorption cross-sections (sigma(s)) at various visible wavelengths, singlet and triplet excited-state lifetimes, and triplet quantum yields of three cyclometalated platinum(II) 4,6-diphenyl-2,2'-bipyridyl complexes, are reported. The presence of metal-metal and pi-pi interactions in the dinuclear and trinuclear complexes results in a significant increase in their respective sigma(g)'s in the visible spectral region. As a result, the ratio of sigma(s)/sigma(g) and sigma(T)/sigma(g) at each wavelength is significantly greater for the mononuclear complex than for the dinuclear and the trinuclear complexes. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码：3688 / 3691
页数：4
相关论文
共 30 条
  • [1] Photophysics and Nonlinear Absorption of Cyclometalated 4,6-Diphenyl-2,2′-bipyridyl Platinum(II) Complexes with Different Acetylide Ligands
    Liu, Rui
    Li, Yunjing
    Li, Yuhao
    Zhu, Hongjun
    Sun, Wenfang
    [J]. JOURNAL OF PHYSICAL CHEMISTRY A, 2010, 114 (48): : 12639 - 12645
  • [2] Mono-, di-, and tri-nuclear complexes of iron(II) with N,N,N',N'-tetramethylethylenediamine
    Davies, SC
    Hughes, DL
    Leigh, GJ
    Sanders, JR
    deSouza, JS
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1997, (11): : 1981 - 1988
  • [3] Binuclear cyclometalated platinum(II) 4,6-diphenyl-2,2′-bipyridine complexes:: Interesting photoluminescent and optical limiting materials
    Sun, WF
    Zhu, HJ
    Barron, PM
    [J]. CHEMISTRY OF MATERIALS, 2006, 18 (10) : 2602 - 2610
  • [4] Assembling mono-, di- and tri-nuclear coordination complexes with a ditopic analogue of 2,2′:6′,2"-terpyridine: syntheses, structures and catalytic studies
    Yin, Zhiwei
    Zhang, Guoqi
    Phoenix, Tonya
    Zheng, Shengping
    Fettinger, James C.
    [J]. RSC ADVANCES, 2015, 5 (45): : 36156 - 36166
  • [5] Photophysics of Pt(II) 4,6-diphenyl-2,2′-bipyridyl complexes in solution and in LB film
    Mathew, Iswarya
    Sun, Wenfang
    [J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2009, 694 (17) : 2750 - 2756
  • [6] Mono-, di-, and tri-nuclear gold(I) complexes with dansyl moiety: Synthesis, characterization, and photophysical properties
    Chao, Hsiu-Yi
    Su, Bo-Chao
    Li, Cheng-Luan
    Lam, Chi-Keung
    Feng, Xiao-Long
    [J]. INORGANIC CHEMISTRY COMMUNICATIONS, 2011, 14 (09) : 1436 - 1439
  • [7] Synthesis, characterization and magnetic studies on mono-, di-, and tri-nuclear Cu(II) complexes of a new versatile diazine ligand
    Anwar, Muhammad U.
    Rawson, Jeremy M.
    Gavey, Emma L.
    Pilkington, Melanie
    Al-Harrasi, Ahmed
    Thompson, Laurence K.
    [J]. DALTON TRANSACTIONS, 2017, 46 (07) : 2105 - 2113
  • [8] Mono-, di- and tri-nuclear manganese(II) complexes derived from a quinquedentate ligand: Superoxide dismutase and catalase mimetic studies
    Kose, Muhammet
    Goring, Paul
    Lucas, Paul
    Mckee, Vickie
    [J]. INORGANICA CHIMICA ACTA, 2015, 435 : 232 - 238
  • [9] Reactions of half-sandwich rhodium(III) and iridium(III) compounds with pyridinethiolate ligands: Mono-, di-, and tri-nuclear complexes
    Wang, Hui
    Guo, Xu-Qing
    Zhong, Rui
    Lin, Yue-Jian
    Zhang, Peng-Cheng
    Hou, Xiu-Feng
    [J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2009, 694 (20) : 3362 - 3368
  • [10] Mono-, di- and tri-nuclear Ni(II) complexes of N-, O-donor ligands: structural diversity and reactivity
    Dey, M
    Rao, CP
    Saarenketo, PK
    Rissanen, K
    [J]. INORGANIC CHEMISTRY COMMUNICATIONS, 2002, 5 (11) : 924 - 928
123