Novel 3D metal-organic framework with pRussian Blue topology:: [Mn(HCOO)3]n•xnH2O

被引：4
|
作者：
Zhou, C.
Li, Y.
Guo, J.
Yang, P.
机构：
[1] Institute of Molecular Science, Shanxi University
[2] College of Chemistry and Chemical Engineering, Shanxi University
来源：
JOURNAL OF STRUCTURAL CHEMISTRY | 2006年 / 47卷 / 04期
关键词：
coordination polymer; three-dimensional framework; porous structure; manganese(III);
D O I：
10.1007/s10947-006-0368-7
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A novel complex, [Mn(HCOO)(3)](n)center dot xnH(2)O, has been synthesized and studied by X-ray crystallography. The structure is trigonal, space group R-3c, a = 8.327(1) angstrom, c = 22.890(6) angstrom, V= 1374.4(5) angstrom(3), Z = 6; final R = 0.045. The crystal structure reveals both O-atoms of the formic acid ligand coordinated to Mn(III) to form a three-dimensional porous framework with the topology of Prussian Blue.
引用
收藏
页码：768 / 770
页数：3
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