Efficient Functionalization of Additives at Supramolecular Material Surfaces

被引:24
|
作者
Goor, Olga J. G. M. [1 ,2 ]
Keizer, Henk M. [3 ]
Bruinen, Anne L. [4 ]
Schmitz, Moniek G. J. [1 ,2 ]
Versteegen, Ron M. [3 ]
Janssen, Henk M. [3 ]
Heeren, Ron M. A. [4 ]
Dankers, Patricia Y. W. [1 ,2 ,5 ]
机构
[1] Eindhoven Univ Technol, Inst Complex Mol Syst, POB 513, NL-5600 MB Eindhoven, Netherlands
[2] Dept Biomed Engn, Biol Chem Lab, POB 513, NL-5600 MB Eindhoven, Netherlands
[3] SyMO Chem BV, Kraneveld 4, NL-5612 AZ Eindhoven, Netherlands
[4] Maastricht Univ, M4I, Maastricht MultiModal Mol Imaging Inst, Univ Singel 50, NL-6229 ER Maastricht, Netherlands
[5] Dept Biomed Engn, Lab Cell & Tissue Engn, POB 513, NL-5600 MB Eindhoven, Netherlands
基金
欧洲研究理事会;
关键词
DIELS-ALDER; THERMOPLASTIC ELASTOMERS; POLYMERS; NANOFIBERS; DIENOPHILES; FABRICATION; SCAFFOLDS; CLICKING; NETWORKS; DESIGN;
D O I
10.1002/adma.201604652
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Selective surface modification reactions can be performed on additives that are supramolecularly incorporated into supramolecular materials. Hereby, processing of the material, that regularly requires harsh processing conditions (i.e., the use of organic solvents and/or high temperatures), and functionalization can be decoupled. Moreover, high-resolution depth profiling by time-of-flight (ToF) secondary-ion mass spectrometry clearly shows distinct differences in surface and bulk material composition.
引用
收藏
页数:8
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