Preparation and water vapor adsorption performance of short-channel mesoporous silica

被引:0
|
作者
Li, Qiwei [1 ,2 ]
He, Zhaohong [2 ,3 ]
Li, Jun [2 ,3 ]
Deng, Lisheng [2 ,3 ]
Zeng, Tao [2 ,3 ]
Huang, Hongyu [2 ,3 ]
机构
[1] Univ Chinese Acad Sci, Beijing 100049, Peoples R China
[2] Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China
[3] South Marine Sci & Engn Guangdong Lab Guangzhou, Guangzhou 511458, Peoples R China
来源
关键词
mesoporous silica; low-temperature calcination; adsorption performance; template removal method; COPOLYMER; TRIBLOCK;
D O I
10.11868/j.issn.1001-4381.2021.001222
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Under the condition of high-speed stirring, the external stress of the molecular assembly process was adjusted to prepare short-channel, rod-shaped ordered mesoporous silica. The effect of different template removal methods on the water vapor adsorption performance of mesoporous silica was studied, and the enhancement method of mesoporous silica adsorption performance was obtained. The method of mesoporous silica adsorption performance. The results show that the short-channel (500-700 nm), rod-shaped mesoporous silica can be prepared, and the temperature at which the templating agent is removed during the preparation process has a greater impact on the surface hydroxyl concentration of the material. The combination of extraction and low-temperature calcination is selected to remove the template, the material obtained by extracting 4 times, calcining 250 celcius has the best water vapor adsorption performance. Under the experimental conditions, the equilibrium adsorption time is about 7.5 min, which is 78.95% of the commercial SBA-15, and the equilibrium adsorption capacity of 0.73 g & BULL;g(-1) is 1.49 times of the commercial SBA-15.
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收藏
页码:95 / 102
页数:8
相关论文
共 22 条
  • [1] AUMONDT PINARDL, 2020, MICROPOROUSANDMESOPO, V296
  • [2] Template removal from mesoporous silicas using different methods as a tool for adjusting their properties
    Barczak, Mariusz
    [J]. NEW JOURNAL OF CHEMISTRY, 2018, 42 (06) : 4182 - 4191
  • [3] Influence of synthesis parameters on the physico-chemical characteristics of SBA-15 type ordered mesoporous silica
    Benamor, Taissire
    Vidal, Loic
    Lebeau, Benedicte
    Marichal, Claire
    [J]. MICROPOROUS AND MESOPOROUS MATERIALS, 2012, 153 : 100 - 114
  • [4] Flash induction calcination: A powerful tool for total template removal and fine tuning of the hydrophobic/hydrophilic balance in SBA-15 type silica mesoporous materials
    Benamor, Taissire
    Michelin, Laure
    Lebeau, Benedicte
    Marichal, Claire
    [J]. MICROPOROUS AND MESOPOROUS MATERIALS, 2012, 147 (01) : 334 - 342
  • [5] Calcination and thermal degradation mechanisms of triblock copolymer template in SBA-15 materials
    Berube, F.
    Kaliaguine, S.
    [J]. MICROPOROUS AND MESOPOROUS MATERIALS, 2008, 115 (03) : 469 - 479
  • [6] Tailored synthesis of SBA-15 rods using different types of acids and its application in adsorption of uranium
    Dan, Hui
    Chen, Luyu
    Xian, Qiang
    Yi, Facheng
    Ding, Yi
    [J]. SEPARATION AND PURIFICATION TECHNOLOGY, 2019, 210 : 491 - 496
  • [7] SBA-15 supported mesoporous Ni and Co catalysts with high coke resistance for dry reforming of methane
    Erdogan, Berna
    Arbag, Huseyin
    Yasyerli, Nail
    [J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2018, 43 (03) : 1396 - 1405
  • [8] Kheshti Z., 2017, INT J NANOSCI NANOTE, V13, P119
  • [9] Process Intensification of Mesoporous Material's Synthesis by Microwave-Assisted Surfactant Removal
    Lopez-Perez, Lidia
    Lopez-Martinez, Marco-Antonio
    Djanashvili, Kristina
    Gora-Marek, Kinga
    Tarach, Karolina A.
    Emma Borges, Maria
    Melian-Cabrera, Ignacio
    [J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2020, 8 (45) : 16814 - 16822
  • [10] An energy-efficient route to the rapid synthesis of organically-modified SBA-15 via ultrasonic template removal
    Pirez, Cyril
    Wilson, Karen
    Lee, Adam F.
    [J]. GREEN CHEMISTRY, 2014, 16 (01) : 197 - 202