[N,N′-Bis(3-methoxy-2-oxidobenzylidene)ethane-1,2-diaminium- κ4O,O′,O",O′"]tris(nitrato-κ2O,O′)-erbium(III)

被引:6
|
作者
Gao, Ting [1 ]
Li, Guang-Ming [1 ]
Gao, Po [1 ]
Yan, Peng-Fei [1 ]
Hou, Guang-Feng [1 ]
机构
[1] Heilongjiang Univ, Sch Chem & Mat Sci, Harbin 150080, Peoples R China
基金
中国国家自然科学基金;
关键词
Data-to-parameter ratio = 15.6; Mean σ(C-C) = 0.004 Å; R factor = 0.022; Single-crystal X-ray study; T = 291 K; WR factor = 0.049;
D O I
10.1107/S1600536809055184
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the mononuclear salen-type complex, [Er(NO3)(3)-(C18H20N2O4)], the Er-III ion is ten-coordinated in a distorted hexadecahedral geometry by six O atoms of three nitrate anions and four O atoms of the salen-like ligand. Intermolecular N-H center dot center dot center dot O hydrogen bonds occur. The crystal structure is stabilized by intermolecular C-H center dot center dot center dot O hydrogen bonds.
引用
收藏
页码:M107 / U249
页数:11
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