Silver-Catalyzed Biomimetic Transfer Hydrogenation of N-Heteroaromatics with Hantzsch Esters as NADH Analogues

被引：14

作者：

Pi, Danwei ^{[1
]}

Zhou, Haifeng ^{[1
]}

Cui, Peng ^{[1
]}

He, Renke ^{[1
]}

Sui, Yuebo ^{[1
]}

机构：

[1] China Three Gorges Univ, Coll Biol & Pharmaceut Sci, Hubei Key Lab Nat Prod Res & Dev, Yichang 443002, Peoples R China

来源：

CHEMISTRYSELECT | 2017年 / 2卷 / 13期

基金：

中国国家自然科学基金;

关键词：

Hantzsch ester; N-heteroaromatics; silver catalysis; transfer hydrogenation; ASYMMETRIC TRANSFER HYDROGENATION; ENANTIOSELECTIVE PROPARGYLATION REACTIONS; TEMPERATURE CO OXIDATION; BRONSTED ACID; CYCLOADDITION REACTIONS; CARBONYL-COMPOUNDS; ETHYLENE OXIDE; REDUCTION; QUINOLINES; DEHYDROGENATION;

D O I：

10.1002/slct.201700327

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A silver-catalyzed biomimetic transfer hydrogenation of Nheteroaromatics with Hantzsch esters as NADH analogues has been developed. The reaction proceeded smoothly under mild conditions to give the corresponding reductive products in up to 99% yield. The asymmetric version of this reaction was also conducted preliminarily with up to 66% ee.

引用

页码：3976 / 3979

页数：4

共 17 条

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