Theoretical investigation of the pathway for reductive cleavage of dinitrogen by a vanadium diamidoamine complex

被引：30
|
作者：
Bates, VME
Clentsmith, GKB
Cloke, FGN
Green, JC
Jenkin, HDL
机构：
[1] Univ Oxford, Inorgan Chem Lab, Oxford OX1 3QR, England
[2] Univ Sussex, Sch Chem Phys & Environm Sci, Chem Lab, Brighton BN1 9QJ, E Sussex, England
来源：
CHEMICAL COMMUNICATIONS | 2000年 / 11期
关键词：
D O I：
10.1039/b002534h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Density functional calculations show that [HN(CH2CH2NH)(2)V] will bind N-2 in a sideways fashion; further reaction with another molecule of [HN(CH2CH2NH)(2)V] leads to reductive cleavage of the N-2 moiety to form a bridged nitrido dimer, [HN(CH2CH2NH)(2)V(mu-N)](2); this study provides a model for the formation of [RN(CH2CH2NR)(2)V(mu-N)](2) (R = SiMe3) by reduction of [RN(CH2CH2NR)(2)V(mu-Cl)](2) under an N-2 atmosphere.
引用
收藏
页码：927 / 928
页数：2
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