Oxazolines as chiral building blocks for imidazolium salts and N-heterocyclic carbene ligands

被引：235

作者：

Glorius, F ^{[1
]}

Altenhoff, G ^{[1
]}

Goddard, R ^{[1
]}

Lehmann, C ^{[1
]}

机构：

[1] Max Planck Inst Kohlenforsch, Kaiser Wilhelm Pl 1, D-45470 Mulheim, Germany

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 22期

关键词：

D O I：

10.1039/b208045a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Enantiomerically pure imidazolium triflates can be readily prepared from bioxazolines and oxazolineimines; deprotonation of imidazolium triflate 2 gives a chiral N-heterocyclic carbene that can act as a ligand in a catalytically active palladium complex.

引用

页码：2704 / +

页数：2

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