OBTAINING Li2CO3 FROM ZINNWALDITE WASTES

A zinnwaldite concentrate with 1.40% Li processed in this study was prepared from zinnwaldite wastes (0.21% Li) using dry magnetic and grain size separations. Zinnwaldite wastes originated from dressing Sn-W ores, which were mined in the past in the Czech Republic in Cinovec area. The extraction process of lithium, so-called gypsum method consisted of sintering the concentrate with CaSO4 and Ca(OH)(2) subsequent leaching of the sinters obtained in H2O, solution purification and precipitation of Li2CO3. It was observed that almost 96% lithium extraction was achieved if sinters prepared at 950 degrees C were leached at 90 degrees C liquid-to-solid ratio = 10:1, reaction time of 10 min. The weight ratio of the concentrate to CaSO4 to Ca(OH)(2) was 6 : 4.2 : 2. Lithium carbonate product containing almost 99% Li2CO3 was separated from the condensed leach liquor, from which calcium was removed by carbonate precipitation.