Synthesis of Substituted Naphthalenes by 1,4-Palladium Migration Involved Annulation with Internal Alkynes

被引：28
|
作者：
Wei, Dong [1 ,2 ]
Hu, Tian-Jiao [2 ]
Feng, Chen-Guo [2 ,3 ]
Lin, Guo-Qiang [1 ,2 ]
机构：
[1] ShanghaiTech Univ, Sch Phys Sci & Technol, Shanghai 200031, Peoples R China
[2] Univ Chinese Acad Sci, Chinese Acad Sci, Key Lab Synthet Chem Nat Subst, Ctr Excellence Mol Synth,Shanghai Inst Organ Chem, Shanghai 200032, Peoples R China
[3] Shanghai Univ Tradit Chinese Med, Innovat Res Inst Tradit Chinese Med, Shanghai 201203, Peoples R China
来源：
CHINESE JOURNAL OF CHEMISTRY | 2018年 / 36卷 / 08期
基金：
中国国家自然科学基金;
关键词：
metal migration; naphthalene; palladium; annulation; alkyne; PALLADIUM-CATALYZED ANNULATION; C-H ACTIVATION; POLYSUBSTITUTED NAPHTHALENES; DERIVATIVES; ARYL; FUNCTIONALIZATION; PHENANTHRENES; 1,4-MIGRATION; HYDROCARBONS; ANNELATION;
D O I：
10.1002/cjoc.201800169
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The palladium catalyzed annulation of 1-bromo-2-vinylbenzene derivatives with internal alkynes was realized for the efficient synthesis of substituted naphthalenes. A controllable aryl to vinylic 1,4-palladium migration process is the key for success.
引用
收藏
页码：743 / 748
页数：6
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