The Application of Platinum and Rhodium N-Heterocyclic Carbene Complexes in Hydrosilylation Reaction

被引：0
|
作者：
Bai Ying [1 ]
Peng Jiajian [1 ]
Hu Yingqian [1 ]
Li Jiayun [1 ]
Lai Guoqiao [1 ]
Jiang Jianxiong [1 ]
机构：
[1] Hangzhou Normal Univ, Minist Educ, Key Lab Organosilicon Chem & Mat Technol, Hangzhou 310012, Zhejiang, Peoples R China
来源：
PROGRESS IN CHEMISTRY | 2009年 / 21卷 / 12期
关键词：
platinum; rhodium; N-heterocyclic carbene; hydrosilylation; INTRAMOLECULAR STETTER REACTION; NUCLEOPHILIC CARBENES; KINETIC RESOLUTION; CATALYTIC-ACTIVITY; ORGANIC CATALYSIS; TRANSESTERIFICATION/ACYLATION REACTIONS; ENANTIOSELECTIVE HYDROSILYLATION; ALPHA; BETA-UNSATURATED ALDEHYDES; PLATINUM(0)-CARBENE COMPLEXES; KETONE HYDROSILYLATION;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
N-heterocyclic carbene Pt and N-heterocyclic carbene Rh complexes are used as catalysts in hydrosilylation. It is specially noticed that the complexes showed excellent catalytic properties and stabilized physical and chemical nature. This review summarizes the recent progress in the application of platinum and rhodium N-heterocyclic carbene complexes as catalysts in hydrosilylation of ketones, alkynes, alkenes and other unsaturated compounds.
引用
收藏
页码：2613 / 2624
页数：12
相关论文
共 87 条
  • [1] [Anonymous], 1992, COMPREHENSIVE HDB HY, DOI DOI 10.1016/C2009-0-11185-6
  • [2] Arai S, 2001, ANGEW CHEM INT EDIT, V40, P234, DOI 10.1002/1521-3773(20010105)40:1<234::AID-ANIE234>3.0.CO
  • [3] 2-K
  • [4] A STABLE CRYSTALLINE CARBENE
    ARDUENGO, AJ
    HARLOW, RL
    KLINE, M
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (01) : 361 - 363
  • [5] ELECTRONIC STABILIZATION OF NUCLEOPHILIC CARBENES
    ARDUENGO, AJ
    DIAS, HVR
    HARLOW, RL
    KLINE, M
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (14) : 5530 - 5534
  • [6] Synthetic and structural studies of NHC-Pt(dvtms) complexes and their application as alkene hydrosilylation catalysts (NHC = N-heterocyclic carbene, dvtms = divinyltetramethylsiloxane)
    Berthon-Gelloz, G
    Buisine, O
    Brière, JF
    Michaud, G
    Stérin, S
    Mignani, G
    Tinant, B
    Declercq, JP
    Chapon, D
    Markó, IE
    [J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2005, 690 (24-25) : 6156 - 6168
  • [7] BO DG, 2006, ORGANOMETALLICS, V25, P1881
  • [8] Stable carbenes
    Bourissou, D
    Guerret, O
    Gabbaï, FP
    Bertrand, G
    [J]. CHEMICAL REVIEWS, 2000, 100 (01) : 39 - 91
  • [9] CYCLOPROPANES FROM REACTIONS OF TRANSITION-METAL CARBENE COMPLEXES WITH OLEFINS
    BROOKHART, M
    STUDABAKER, WB
    [J]. CHEMICAL REVIEWS, 1987, 87 (02) : 411 - 432
  • [10] Organocatalyzed conjugate umpolung of α,β-unsaturated aldehydes for the synthesis of γ-butyrolactones
    Burstein, C
    Glorius, F
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (45) : 6205 - 6208
123456789