Rate of methane-steam reforming reaction on the surface of molten BF slag - for heat recovery from molten slag by using a chemical reaction

被引:94
|
作者
Kasai, E
Kitajima, T
Akiyama, T
Yagi, J
Saito, F
机构
[1] TOHOKU UNIV,FAC ENGN,AOBA KU,SENDAI,MIYAGI 98077,JAPAN
[2] MIYAGI NATL COLL TECHNOL,NATORI,MIYAGI 983,JAPAN
关键词
heat recovery; base metals; molten slag; methane-steam reforming; chemical reaction rate; blast furnace;
D O I
10.2355/isijinternational.37.1031
中图分类号
TF [冶金工业];
学科分类号
0806 ;
摘要
A new concept for heal recovery from molten slag has been proposed. It involves exchanging energy between sensible heat of slag and chemical energy of gas mixture through methane-steam reforming and its reverse reactions. The validity of this concept was fundamentally verified by obtaining kinetic data on the reforming reaction using molten blast furnace slag samples. This includes essential information such as temperature dependence and effects of composition of reactant gas on the chemical reaction rate. The sulfur containing in slag is also found to play a significant role in the reforming reaction.
引用
收藏
页码:1031 / 1036
页数:6
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