Mean-square radius of gyration of poly[oxy(1-alkylethylenes)]

被引：0
|
作者：
Zhou, ZP [1 ]
Yan, DY [1 ]
机构：
[1] SHANGHAI JIAO TONG UNIV,DEPT APPL CHEM,SHANGHAI 200030,PEOPLES R CHINA
来源：
POLYMERS FOR ADVANCED TECHNOLOGIES | 1997年 / 8卷 / 04期
关键词：
radius of gyration; conformational statistics; unperturbed dimension of polymer;
D O I：
暂无
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Taking account of the influences of both side groups and hetero-atoms in backbone, the mean-square radius of gyration of poly[oxy(1-alkylethylenes)] has been derived by the method of the rotational isomeric state approximation and matrix algebra. Numerical calculation with the parameters available in literature indicated that the dependence of [S-2] on the molecular weight call be expressed as the general formula, [S-2] = aM(b) with b = 1 +/- 0.02, for poly(oxypropylene), poly[oxy(1-ethylethylene)] and poly[oxy(1-tert-butylethylene)]. (C) 1997 by John Wiley & Sons, Ltd.
引用
收藏
页码：270 / 274
页数：5
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