Enantioselective nitrogen transfer to sulfides from nitridomanganese(V) complexes

被引：0

作者：

Tomooka, CS ^{[1
]}

Carreira, EM ^{[1
]}

机构：

[1] ETH Honggerberg, Organ Chem Lab, CH-8093 Zurich, Switzerland

来源：

HELVETICA CHIMICA ACTA | 2002年 / 85卷 / 11期

关键词：

D O I：

10.1002/1522-2675(200211)85:11<3773::AID-HLCA3773>3.0.CO;2-O

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We describe the facile preparation of novel, optically active nitridomanganese(V) complexes which serve as reagents for the electrophilic amination of sulfides. This amination method has several appealing features, including: i) the facile preparation of large quantities of the starting nitridomanganese reagent 3, ii) the preparation of acylsulfilimines 2 in optically active form, and iii) the mild reaction conditions employed.

引用

页码：3773 / 3784

页数：12

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