Adenine-containing block copolymers via ring-opening metathesis polymerization: Synthesis and self-assembly into rod morphologies

被引：92
|
作者：
Bazzi, HS [1 ]
Sleiman, HF [1 ]
机构：
[1] McGill Univ, Dept Chem, Montreal, PQ H3A 2K6, Canada
来源：
MACROMOLECULES | 2002年 / 35卷 / 26期
关键词：
D O I：
10.1021/ma025676o
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The first synthesis of adenine-containing polymers and block copolymers using the ring-opening metathesis polymerization of non-covalently protected monomers are shown. Studies of the copolymer 9 reveal an unexpected cylindrical morphology, which can be interpreted as arising from the hydrogen-bonding self-complementarity of the adenine units in the micellar core. Thus, further studies are currently conducted to fully characterize this morphogenesis mechanism as well as to study the effect of hydrogen-bonding guests on the polymer morphologies.
引用
收藏
页码：9617 / 9620
页数：4
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