Investigations of hydrogen bonding in the poly(urethane-urea)-based membrane materials by using FTIR spectroscopy

被引：17
|
作者：
Wolinska-Grabczyk, Aleksandra [1 ]
Kaczmarczyk, Bozena [1 ]
Jankowski, Andrzej [1 ]
机构：
[1] Polish Acad Sci, Ctr Polymer & Carbon Mat, PL-41819 Zabrze, Poland
来源：
POLISH JOURNAL OF CHEMICAL TECHNOLOGY | 2008年 / 10卷 / 04期
关键词：
Infrared spectroscopy; hydrogen bonding; polyurethanes;
D O I：
10.2478/v10026-008-0049-8
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
FTIR analysis was used to study the hydrogen bonding in 4,4'-diaminodiphenylmethane-based segmented poly(urethane-urea)s varying in the length of the poly(tetramethylene oxide) (PTMO)-based soft segments. Experiments were designed to follow the IR absorption of both the NH and carbonyl regions as a function of temperature in order to directly investigate the extent and strength of the hydrogen bonds, and thereby to gain some information about the possible alteration of the initial phase-segregated morphology as a result of the applied thermal treatment.
引用
收藏
页码：53 / 56
页数：4
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