Synthesis and structure of (H2O)(12-crown-4)-Co(II)(Co(II)Cl-3)(mu-Cl) isolated from a liquid clathrate medium

被引：3

作者：

MacGillivray, LR ^{[1
]}

Atwood, JL ^{[1
]}

机构：

[1] UNIV MISSOURI,DEPT CHEM,COLUMBIA,MO 65211

来源：

JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 1997年 / 27卷 / 08期

基金：

美国国家科学基金会; 加拿大自然科学与工程研究理事会;

关键词：

liquid clathrate; cobalt(II) chloride; 12-crown-4;

D O I：

10.1007/BF02576583

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The crystal structure of (H2O)(12-crown-4)Co(II)(Co(II)Cl-3)(mu-Cl) 1 is reported. Crystal data for 1: monoclinic, space group P2(1)/m, a = 7.958(8) Angstrom, b = 12.006(1) Angstrom, c = 69.017(9) Angstrom, beta = 107.896(2)degrees, D-c = 1.84 g cm(-3), Z = 2, R1 = 0.025, wR2 = 0.059, The crown ether acts as a tetradentate ligand and partially completes the binding sphere of the Co(II) ion which also includes one water oxygen atom and a bridging chloride ligand, the latter of which maybe regarded to originate from a [CoCl4](2-) ion.

引用

页码：453 / 456

页数：4

共 50 条

[1] Synthesis and structure of (H2O)(12-crown-4)-Co(II)(Co(II)Cl3)(μ-Cl) isolated from a liquid clathrate medium
Leonard R. MacGillivray
Jerry L. Atwood
Journal of Chemical Crystallography, 1997, 27 : 453 - 456
[2] Dynamic electrochemistry of cis[Co(EN)(2)(ENH)Cl]Cl-3 center dot H2O and [Co(EN)(3)]Cl-3 complexes
Wilgocki, M
Baczynski, S
Cyfert, M
Giera, E
Jaroszewski, M
JOURNAL OF COORDINATION CHEMISTRY, 1995, 34 (02) : 99 - 117
[3] Crystal Structure of[La（NO3）3（12-crown-4）-（H2O）]（12-crown-4）
Mao Jiang-Gao
Jin Zhong-Sheng
Yu Feng-Lan (Laboratory of Rare Earth Chemistry and Physics
结构化学, 1994, (04) : 281 - 284
[4] DINUCLEAR CYCLOPENTADIENYL CARBONYL AND ALKYNE COMPLEXES OF NIOBIUM(II) AND TANTALUM(II) - STRUCTURES OF [(C5H4ME)NB(MU-CL)(CO)2]2, [(C5H4ME)NB(MU-CL)(ARC=CAR)]2, AND [(C5ME5)TA(MU-CL)(CO)2]2
KWON, D
REAL, J
CURTIS, MD
RHEINGOLD, A
HAGGERTY, BS
ORGANOMETALLICS, 1991, 10 (01) : 143 - 148
[5] CRYSTALLINE-STRUCTURE OF PRODUCTS OF MOO(12-CROWN-4)CL3-BULLET-H2O AND REO(12-CROWN-4)BR3-BULLET-H2O HYDROLYSIS
SERGIENKO, VS
ILYUKHIN, AB
LUZIKOVA, AV
PORAIKOSHITS, MA
KOORDINATSIONNAYA KHIMIYA, 1991, 17 (11): : 1489 - 1496
[6] LIQUID CLATHRATE MEDIA CONTAINING TRANSITION-METAL HALOCARBONYL ANIONS - FORMATION AND CRYSTAL-STRUCTURES OF [K+CENTER-DOT-18-CROWN-6][CR(CO)(5)CL], [H3O+CENTER-DOT-18-CROWN-6][W(CO)(5)CL], [H3O+CENTER-DOT-18-CROWN-6][W(CO)(4)CL-3], AND [H2O-CENTER-DOT-BIS-AZA-18-CROWN-6-CENTER-DOT(H+)(2)][W(CO)(4)CL-3](2)
ATWOOD, JL
BOTT, SG
JUNK, PC
MAY, MT
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1995, 487 (1-2) : 7 - 15
[7] Synthesis and structural characterization of a series of hydrido osmium-palladium carbonyl clusters: [Os5Pd(CO)(16)H-n+4(mu-Cl)(2-n)] (n=0-2), [{Os3Pd(CO)(9)-(mu-H)(2)(mu-Cl)}(mu-Cl)(2)]center dot H2O and [Os4Pd(CO)(11)(mu-H)(3)(mu-Cl)(3)(C5H5N)]center dot 0.5C(6)H(14)
Chan, S
Wong, WT
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1995, (24): : 3987 - 3994
[8] Synthesis and crystal structures [Co(2,3-tri)2Cl]•ZnCl4•Cl•H2O and [Co(amp)3]•amph•Cl•2ZnCl4•H2O
Zhang Yun-Qian
Zhu Qian-Jiang
Xue Sai-Feng
Tao Zhu
CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2007, 23 (09) : 1523 - 1527
[9] Synthesis and crystal structure of a polyheteronuclear complex, [Co(III)(Hdmg)2(H2O)2Mn(II)Cl3]
Wang, SY
CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2004, 20 (02) : 178 - 180
[10] THE SYNTHESIS, MOLECULAR-STRUCTURE AND MAGNETIC-PROPERTIES OF [NI2L(MU-CL)CL2(H2O)2].2H2O.(C2H5OH)0.42 AND [CO2L(MU-CL)CL2]. (H2O)0.18 (L = 2,6-BIS-(N,N'-DIMETHYLETHYLENENAMINEFORMIDOYL)-4-METHYLPHENOLATO)
QUIJANO, ER
STEVENS, ED
OCONNOR, CJ
INORGANICA CHIMICA ACTA, 1990, 177 (02) : 267 - 275

← 1 2 3 4 5 →