The nature of the colloidal 'glass' transition

被引:21
|
作者
Dawson, KA [1 ]
Lawlor, A
De Gregorio, P
McCullagh, GD
Zaccarelli, E
Foffi, G
Tartaglia, P
机构
[1] Univ Coll Dublin, Irish Ctr Colloid Sci & Biomat, Dept Chem, Dublin 4, Ireland
[2] Univ Roma La Sapienza, Ctr Stat Mech & Complex, INFM, Dipartimento Fis, I-00185 Rome, Italy
关键词
D O I
10.1039/b204624e
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The dynamically arrested state of matter is discussed in the context of athermal systems, such as the hard sphere colloidal arrest. We believe that the singular dynamical behaviour near arrest expressed, for example, in how the diffusion constant vanishes may be universal, in a sense to be discussed in the paper. Based on this we argue the merits of studying the problem with simple lattice models. This, by analogy with the the critical point of the Ising model, should lead us to clarify the questions, and begin the program of establishing the degree of universality to be expected. We deal only with ideal athermal dynamical arrest transitions, such as those found for hard sphere systems. However, it is argued that dynamically available volume (DAV) is the relevant order parameter of the transition, and that universal mechanisms may be well expressed in terms of DAV. For simple lattice models we give examples of simple laws that emerge near the dynamical arrest, emphasising the idea of a near-ideal gas of holes, interacting to give the power law diffusion constant scaling near the arrest. We also seek to open the discussion of the possibility of an underlying weak coupling theory of the dynamical arrest transition, based on DAV.
引用
收藏
页码:13 / 26
页数:14
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