Synthesis of clusters Fe-2(CO)(6)(mu-XCH2CH=CH2)(mu(3)-X)Fe(CO)(2)Cp (X = Se, S; Cp = eta(5)-C5H5)

被引：1

作者：

Konchenko, SN

Maksakov, VA

Filippov, IY

Varnek, VA

机构：

[1] Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, 630090 Novosibirsk

来源：

RUSSIAN CHEMICAL BULLETIN | 1997年 / 46卷 / 07期

关键词：

carbonyl clusters; cluster monomers; iron; sulfur; selenium; synthesis;

D O I：

10.1007/BF02495934

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The clusters Fe-2(CO)(6)(mu-XCH2CH=CH2)(mu(3)-X)Fe(CO)(2)Cp (X = S, Se) were prepared by the successive treatment of the bi-and trimetallic complexes Fe-2(CO)(6)(mu-Se-2) and Fe-3(CO)(9)(mu(3)-X) with allylmagnesium chloride and CpFe(CO)(2)I. The clusters obtained contain a noncoordinated C=C bond. The structure of the Se-containing cluster was suggested on the basis of comparison of its spectral data (IR, H-1 NMR, and Mossbauer spectral with the spectra of the analogous S-containing complex, which was previously characterized by X-ray diffraction analysis.

引用

页码：1317 / 1320

页数：4

共 50 条

[1] Synthesis of clusters Fe2(CO)6(μ-XCH2CH=CH2)(μ3-X)Fe(CO)2Cp (X = Se, S; Cp = η5-C5H5)
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V. A. Maksakov
I. Yu. Filippov
V. A. Varnek
[J]. Russian Chemical Bulletin, 1997, 46 : 1317 - 1320
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Jones, PG
Laube, J
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