Construction of a new solid-state U(VI) ion-selective electrode based on polypyrrole conducting polymer

In this study, a potentiometric sensor based on a pencil graphite electrode (PGE) coated with polypyrrole doped with uranyl zinc acetate (termed PGE/PPy/U) have been prepared for potentiometric determination of uranyl in aqueous solutions. Electropolymerization reaction for preparing of U(VI) sensor electrode was carried via applying a constant current of 1.0 mA on PGA working electrode in a solution containing 8.0 mM pyrrole and 0.8 mM ZnUO2(CH3COO)(4) salt. The constructed electrode displayed a linear and near Nernstian response (22.60 +/- 0.40 mV/decade) to U(VI) ions in the concentration range of 1.0 x 10(-6)-1.0 x 10(-2) M. A detection limit of 6.30 x 10(-7) M and a fast response time (<= 12 s) was observed during measurements. The working pH range of the electrode was 4.0-8.0 and lifetime of the sensor was at least 60 days. The electrode revealed good selectivity with respect to many cations including alkali, alkaline earth, transition and heavy metal ions. The introduced uranyl electrode was used for measurement of U(VI) ion in real samples without any serious inferences from other ions.