Magnetic Nanoparticles Impregnated, Cross-Linked, Porous Chitosan Microspheres for Efficient Adsorption of Methylene Blue from Pharmaceutical Waste Water

被引:21
|
作者
Jyothi, M. S. [1 ,2 ]
Angadi, V. Jagadeesha [3 ]
Kanakalakshmi, T. V. [1 ]
Padaki, Mahesh [1 ]
Geetha, Balakrishna R. [1 ]
Soontarapa, Khantong [2 ]
机构
[1] Jain Univ, Ctr Nano & Mat Sci, Jain Global Campus, Bangalore 562112, Karnataka, India
[2] Chulalongkorn Univ, Ctr Excellence Petrochem & Mat Technol, Fac Sci, Dept Chem Technol, Phayathai Rd, Bangkok 10330, Thailand
[3] Presidency Univ, Sch Engn, Dept Phys, Bangalore 560064, Karnataka, India
关键词
Manganese ferrite; Chitosan; Adsorption; Kinetics; Methylene blue; ACTIVATED CARBON; PHOTOCATALYTIC MECHANISM; REMOVAL; OXIDE; THERMODYNAMICS; ADSORBENT; KINETICS; ISOTHERM; CORE; IONS;
D O I
10.1007/s10924-019-01531-x
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The study demonstrates the preparation of MnFe2O4 impregnated chitosan-microspheres (CMMS) as adsorbents for efficient removal of cationic thiazine dye, methylene blue. A facile approach with great economic and technical advantages to obtain highly crystalline manganese ferrite nanoparticles by solution combustion method is accounted. CMMS were characterized and evaluated for MB adsorption using linear forms of Freundlich and Langmuir adsorption isotherms, pseudo-first order, pseudo-second order and Elovich kinetic models. Application of CMMS to pharmaceutical waste, desorption of MB and reusability of CMMS are reported. Significantly, MB concentration in treated real sample was reduced by similar to 18 times to that of initial concentration.
引用
收藏
页码:2408 / 2418
页数:11
相关论文
共 50 条
  • [1] Magnetic Nanoparticles Impregnated, Cross-Linked, Porous Chitosan Microspheres for Efficient Adsorption of Methylene Blue from Pharmaceutical Waste Water
    M. S. Jyothi
    V. Jagadeesha Angadi
    T. V. Kanakalakshmi
    Mahesh Padaki
    Balakrishna R. Geetha
    Khantong Soontarapa
    [J]. Journal of Polymers and the Environment, 2019, 27 : 2408 - 2418
  • [2] Synthesis of magnetic epichlorohydrin cross-linked carboxymethyl cellulose microspheres and their adsorption behavior for methylene blue
    Lin, Qingwen
    Chang, Jiali
    Gao, Mengfan
    Ma, Hongzhu
    [J]. JOURNAL OF ENVIRONMENTAL SCIENCE AND HEALTH PART A-TOXIC/HAZARDOUS SUBSTANCES & ENVIRONMENTAL ENGINEERING, 2017, 52 (02): : 106 - 116
  • [3] Adsorption of methylene blue by graphene immobilized cross-linked chitosan beads
    Ren, Baixiang
    Duan, Xiaoyue
    Wang, Yinan
    [J]. DESALINATION AND WATER TREATMENT, 2019, 140 : 347 - 355
  • [4] Cross-linked chitosan microspheres: An efficient and eco-friendly adsorbent for iodide removal from waste water
    Zhang, Wenjun
    Li, Qing
    Mao, Qian
    He, Gaohong
    [J]. CARBOHYDRATE POLYMERS, 2019, 209 : 215 - 222
  • [5] Chitosan cross-linked graphene oxide/lignosulfonate composite aerogel for enhanced adsorption of methylene blue in water
    Yan, Mingfang
    Huang, Wenxing
    Li, Zhili
    [J]. INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES, 2019, 136 : 927 - 935
  • [6] Cross-linked chitosan/sepiolite composite for the adsorption of methylene blue and reactive orange 16
    Marrakchi, F.
    Khanday, W. A.
    Asif, M.
    Hameed, B. H.
    [J]. INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES, 2016, 93 : 1231 - 1239
  • [7] Uptake of methylene blue on divinylbenzene cross-linked chitosan/maleic anhydride polymer by adsorption process
    Liu, Xiaolin
    Zhang, Yong
    Ju, Hui
    Yang, Fan
    Luo, Xuan
    Zhang, Lin
    [J]. COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2021, 629
  • [8] Adsorption of food dyes from aqueous solution by glutaraldehyde cross-linked magnetic chitosan nanoparticles
    Zhou, Zhengkun
    Lin, Shiqi
    Yue, Tianli
    Lee, Tung-Ching
    [J]. JOURNAL OF FOOD ENGINEERING, 2014, 126 : 133 - 141
  • [9] Cross-linked succinyl chitosan as an adsorbent for the removal of Methylene Blue from aqueous solution
    Huang, Xiao-Yi
    Bu, Huai-Tian
    Jiang, Gang-Biao
    Zeng, Ming-Hua
    [J]. INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES, 2011, 49 (04) : 643 - 651
  • [10] Adsorption of allura red dye by cross-linked chitosan from shrimp waste
    Sanchez-Duarte, Reyna G.
    Sanchez-Machado, Dalia I.
    Lopez-Cervantes, Jaime
    Correa-Murrieta, Ma. A.
    [J]. WATER SCIENCE AND TECHNOLOGY, 2012, 65 (04) : 618 - 623