Ni(II) ternary complexes containing diimine and cysteine

被引：0
|
作者：
Bancu, Laura [1 ]
Carp, Oana
Stanica, Nicolae
Jitaru, Ioana
机构：
[1] Politehn Univ, Fac Appl Chem & Mat Sci, Polizu St 1, Bucharest 011061, Romania
[2] Roumanian Acad, I Murgulescu Inst Phys Chem, Bucharest 060021, Romania
来源：
REVUE ROUMAINE DE CHIMIE | 2006年 / 51卷 / 06期
关键词：
ternary Ni(II) complexes; cysteine; 2,2 '-bypiridine; nickel enzyme;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
This paper deals with the synthesis and characterization of new ternary [Ni(diimine)(thiolate)21 complexes where diimine is 2,2'-bypiridine (bpy) or its 4,4'-derivates: 4,4'-dimethyl-2,2'-bypiridine (dmbpy) and 4,4'-dinitro-2,2'-bypiridine (dnbpy) and thiolate is thioaminoacid cysteine (Cys) or its methylic ester (CysMe) in which Ni lies in a square planar N2S2 environment. The investigation on the presence of ligand-ligand electron transfer processes in these complex compounds and of the factors these processes depends on are also studied. The complex compounds are suitable for being metalloenzyme simple in vitro models.
引用
收藏
页码：497 / 502
页数：6
相关论文
共 50 条
  • [1] TERNARY CU(II) AND NI(II) COMPLEXES CONTAINING AROMATIC ALDIMINES
    KOHLI, RK
    BHATTACHARYA, PK
    [J]. INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 1977, 15 (06): : 566 - 568
  • [2] Luminescent α-diimine complexes of ruthenium(II) containing scorpionate ligands
    Huang, L
    Seward, KJ
    Sullivan, BP
    Jones, WE
    Mecholsky, JJ
    Dressick, WJ
    [J]. INORGANICA CHIMICA ACTA, 2000, 310 (02) : 227 - 236
  • [3] Olefin polymerizations using cationic Ni(II) and Pd(II) diimine complexes
    Brookhart, M
    Johnnson, LK
    Killian, CM
    Svejda, SA
    Gates, D
    Tempel, DJ
    Huff, RL
    Leatherman, MD
    [J]. MACROMOLECULAR SYMPOSIA, 2001, 174 : 29 - 30
  • [4] TERNARY COMPLEXES OF NI(II) WITH ETHYLENEDIAMINE AND NUCLEOTIDES
    FIOL, JJ
    TERRON, A
    AGUILO, M
    MORENO, V
    SOLANS, X
    [J]. RECUEIL DES TRAVAUX CHIMIQUES DES PAYS-BAS-JOURNAL OF THE ROYAL NETHERLANDS CHEMICAL SOCIETY, 1987, 106 (6-7): : 200 - 200
  • [5] SOLVATION EFFECTS IN PEROXODISULFATE OXIDATION OF TERNARY IRON(II)-CYANIDE DIIMINE COMPLEXES
    BLUNDELL, NJ
    BURGESS, J
    GUARDADO, P
    HUBBARD, CD
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1990, 199 : 249 - INOR
  • [6] COBALT(II) AND ZINC(II) COMPLEXES OF CYSTEINE CONTAINING DIPEPTIDES
    SOVAGO, I
    KISS, T
    VARNAGY, K
    REVEREND, BD
    [J]. POLYHEDRON, 1988, 7 (12) : 1089 - 1093
  • [7] Binary and ternary complexes of Cu(II) ions with saccharin and cysteine
    Çakir, S
    Biçer, E
    Çakir, O
    [J]. ELECTROCHEMISTRY COMMUNICATIONS, 2000, 2 (02) : 124 - 129
  • [8] Luminescent Cyanoruthenate(II)-Diimine and Cyanoruthenium(II)-Diimine Complexes
    Feng, Hua
    Zhang, Feng
    Lai, Sze-Wing
    Yiu, Shek-Man
    Ko, Chi-Chiu
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2013, 19 (45) : 15190 - 15198
  • [9] POTENTIOMETRIC STUDIES ON TERNARY COMPLEXES OF CU(II) AND NI(II)
    KUMARI, V
    SHARMA, RC
    CHATURVEDI, GK
    [J]. BULLETIN DE L ACADEMIE POLONAISE DES SCIENCES-SERIE DES SCIENCES CHIMIQUES, 1975, 23 (04): : 295 - 299
  • [10] Ethylene polymerization by sterically and electronically modulated Ni(II) α-diimine complexes
    Bahuleyan, Bijal Kottukkal
    Son, Gi Wan
    Park, Dae-Won
    Ha, Chang-Sik
    Kim, Il
    [J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2008, 46 (03) : 1066 - 1082
12345