Nonlinear frequency response analysis of PEM fuel cells for diagnosis of dehydration, flooding and CO-poisoning

被引：84

作者：

Kadyk, Thomas ^{[1
,2
]}

Hanke-Rauschenbach, Richard ^{[1
]}

Sundmacher, Kai ^{[1
,2
]}

机构：

[1] Max Planck Inst Dynam Complex Tech Syst, D-39106 Magdeburg, Germany

[2] Otto VonGuericke Univ Magdegurg, D-39106 Magdeburg, Germany

来源：

JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 2009年 / 630卷 / 1-2期

关键词：

Polymer electrolyte membrane fuel cell; Nonlinear frequency response analysis; Higher order frequency response function; Flooding; Membrane drying; Catalyst poisoning; ELECTROCHEMICAL IMPEDANCE SPECTROSCOPY; AC-IMPEDANCE; HYDROGEN ELECTRODES; EIS INVESTIGATIONS; STEADY-STATE; PART I; MODEL; WATER; DISTORTIONS; MANAGEMENT;

D O I：

10.1016/j.jelechem.2009.02.001

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Membrane dehydration, fuel cell flooding and anode catalyst poisoning by carbon monoxide are diagnosed in a single polymer electrolyte fuel cell (PEMFC) using nonlinear frequency response analysis (NFRA). A sinusoidal perturbation of high amplitude is applied to the fuel cell current and the resulting voltage is analysed using the concept of higher order frequency response functions. It is shown that the linear part of the system response corresponds to classical Electrochemical Impedance Spectra (EIS), which are not sufficient to clearly distinguish between different fuel cell failures. Therefore, the nonlinear behaviour is additionally taken into account in the form of the second order frequency response function. With this, it is possible to distinguish unambiguously between the three analysed PEM fuel cell failures. (C) 2009 Elsevier B.V. All rights reserved.

引用

页码：19 / 27

页数：9

共 36 条

[1] Electrochemical impedance study of anode CO-poisoning in PEM fuel cells
Ciureanu, M
Wang, H
[J]. JOURNAL OF NEW MATERIALS FOR ELECTROCHEMICAL SYSTEMS, 2000, 3 (02) : 107 - 119
[2] Nonlinear frequency response analysis for the diagnosis of carbon monoxide poisoning in PEM fuel cell anodes
Thomas Kadyk
Richard Hanke-Rauschenbach
Kai Sundmacher
[J]. Journal of Applied Electrochemistry, 2011, 41 : 1021 - 1032
[3] Nonlinear frequency response analysis for the diagnosis of carbon monoxide poisoning in PEM fuel cell anodes
Kadyk, Thomas
Hanke-Rauschenbach, Richard
Sundmacher, Kai
[J]. JOURNAL OF APPLIED ELECTROCHEMISTRY, 2011, 41 (09) : 1021 - 1032
[4] An improved model to predict flooding/dehydration in PEM fuel cells
Maharudrayya, S.
Jayanti, S.
Deshpande, A. P.
[J]. Proceedings of the 3rd International Conference on Fuel Cell Science, Engineering, and Technology, 2005, : 71 - 77
[5] Nonlinear Impedance Spectra Analysis of CO Poisoning on PEM Fuel Cell Performance
Pachimatla, Rajesh
Srinivasan, Ramanathan
[J]. MULTISCALE MODELING, SIMULATION AND DESIGN - FROM CONVENTIONAL METHODS TO THE LATEST IN DATA SCIENCE, 2018, 85 (05): : 67 - 76
[6] Nonlinear frequency response analysis of dehydration phenomena in polymer electrolyte membrane fuel cells
Kadyk, Thomas
Hanke-Rauschenbach, Richard
Sundmacher, Kai
[J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2012, 37 (09) : 7689 - 7701
[7] Modeling and simulation of PEM fuel cells with CO poisoning
Baschuk, JJ
Rowe, AM
Li, XG
[J]. JOURNAL OF ENERGY RESOURCES TECHNOLOGY-TRANSACTIONS OF THE ASME, 2003, 125 (02): : 94 - 100
[8] Experimental and modelling studies of CO poisoning in PEM fuel cells
Farrell, C. G.
Gardner, C. L.
Ternan, M.
[J]. JOURNAL OF POWER SOURCES, 2007, 171 (02) : 282 - 293
[9] An analysis of fluidic voltage statistical correlation for a diagnosis of PEM fuel cell flooding
Giurgea, S.
Tirnovan, R.
Hissel, D.
Outbib, R.
[J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2013, 38 (11) : 4689 - 4696
[10] Predicting the Performance of PEM Fuel Cells by Determining Dehydration or Flooding in the Cell Using Machine Learning Models
Zaveri, Jaydev Chetan
Dhanushkodi, Shankar Raman
Kumar, C. Ramesh
Taler, Jan
Majdak, Marek
Weglowski, Bohdan
[J]. ENERGIES, 2023, 16 (19)

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