Luminesence properties of rare-earth ions in organic-inorganic hybrid mesostructured thin films

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作者
Franville, AC [1 ]
Dunn, B [1 ]
Zink, JI [1 ]
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[1] Univ Clermont Ferrand, CNRS, UMR 6002, Lab Mat Inorgan, F-63174 Aubiere, France
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TB33 [复合材料];
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摘要
This paper describes the preparation of hybrid surfactant-templated thin films functionalized with rare-earth (Eu3+ and Tb3+ organic complexes. 2-D hexagonally ordered films are obtained by a one-pot synthesis process based on an acid-catalyzed approach. Ln(3+) ions are coordinated to bis-silylated ligands that co-polymerize with TEOS, which enables one-to incorporate the fluorescent centers within the silica framework. Luminescent properties of the organic-inorganic mesostructured films are discussed and compared to those of amorphous samples with similar composition.
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页码:199 / 204
页数:6
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